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Effect of γ-alumina nanorods on CO hydrogenation to higher alcohols over lithium-promoted CuZn-based catalysts
Applied Catalysis A: General ( IF 5.5 ) Pub Date : 2017-10-05 , DOI: 10.1016/j.apcata.2017.10.001
SuMin Choi , YoungJong Kang , SangWoo Kim

To achieve high catalytic activities and long-term stability to produce higher alcohols via CO hydrogenation, the catalytic activities were tuned by controlling the loading amounts of γ-alumina nanorods and Al3+ ions added to modify Cu-Zn catalysts promoted with Li. The selectivity of higher alcohols and the CO conversion to higher alcohols over a Li-modified Cu0.45Zn0.45Al0.1 catalyst supported on 10% nanorods were 1.8 and 2.7 times higher than those with a Cu-Zn catalyst without nanorods and Al3+ ions, respectively. The introduction of the thermally and chemically stable γ-Al2O3 nanorod support and of Al3+ to the modified catalysts improves the catalytic activities by decreasing the crystalline size of CuO and increasing the total basicity. Along with the nanorods, a refractory CuAl2O4 formed by the thermal reaction of CuO and Al3+ enhances the long-term stability by increasing the resistance to sintering of the catalyst.



中文翻译:

锂促进的CuZn基催化剂上γ-氧化铝纳米棒对CO加氢成高级醇的影响

为了实现高催化活性和通过CO加氢生产高级醇的长期稳定性,可通过控制γ-氧化铝纳米棒和Al 3+离子的负载量来调节催化活性,其中Al 3+离子用于改性由Li促进的Cu-Zn催化剂。在10%的纳米棒上负载的Li改性的Cu 0.45 Zn 0.45 Al 0.1催化剂上,高级醇的选择性和CO转化为高级醇的效率分别是不使用纳米棒和Al 3+离子的Cu-Zn催化剂的1.8和2.7倍, 分别。在引入热和化学稳定的γ-Al的2 ö 3纳米棒支撑和Al 3+通过减小CuO的晶体尺寸并增加总碱度,改性催化剂的改性提高了催化活性。与纳米棒一起,由CuO和Al 3+的热反应形成的难熔CuAl 2 O 4通过增加催化剂的烧结阻力而提高了长期稳定性。

更新日期:2017-10-05
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