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Continuous flow synthesis of poly(acrylic acid) via free radical polymerisation
Reaction Chemistry & Engineering ( IF 3.9 ) Pub Date : 2017-07-14 00:00:00 , DOI: 10.1039/c7re00063d
Laurens Brocken 1, 2, 3, 4 , Paul D. Price 4, 5, 6 , Jane Whittaker 4, 5, 6 , Ian R. Baxendale 1, 2, 3, 4
Affiliation  

The free radical polymerisation of aqueous solutions of acrylic acid (1) has been studied using a continuous flow reactor to quickly screen reaction parameters such as temperature, residence time, monomer- and initiator concentration. The experimental data sets produced established a theoretical basis for conducting scale up processes to efficiently produce larger quantities of poly(acrylic acid) delivered with good control over the molecular weight and dispersity.

中文翻译:

通过自由基聚合连续流动合成聚丙烯酸

已使用连续流动反应器研究丙烯酸水溶液(1)的自由基聚合反应,以快速筛选反应参数,例如温度,停留时间,单体和引发剂浓度。产生的实验数据集为进行按比例放大的过程建立了理论基础,以有效地生产大量的聚丙烯酸,并且可以很好地控制分子量和分散度。
更新日期:2017-10-03
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