A novel solid-state synthetic approach has been developed for the generation of conjugated nanoporous polymer networks. Using mechanochemical-assisted oxidative coupling polymerization, we demonstrated a rapid and solvent-free synthesis of conjugated polycarbazoles with high porosities and promising CO₂ storage abilities. This innovative approach constitutes a new direction for the development of novel nanoporous polymer frameworks through sustainable solid-state assembly pathways, and may open up new possibilities for the rational design and synthesis of nanoporous materials for carbon capture.

中文翻译：

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共轭纳米多孔聚咔唑的固态合成

已经开发了一种新型固态合成方法来生成共轭纳米多孔聚合物网络。使用机械化学辅助氧化偶联聚合，我们展示了一种快速且无溶剂的共轭聚咔唑合成方法，该共轭聚咔唑具有高孔隙率和良好的 CO ₂储存能力。这种创新方法构成了通过可持续固态组装途径开发新型纳米多孔聚合物框架的新方向，并可能为碳捕获纳米多孔材料的合理设计和合成开辟新的可能性。