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Coupling Reactions: A Conjugated Microporous Polymer for Palladium‐Free, Visible Light‐Promoted Photocatalytic Stille‐Type Coupling Reactions (Adv. Sci. 8/2017)
Advanced Science ( IF 15.1 ) Pub Date : 2017-08-22 , DOI: 10.1002/advs.201770042
Saman Ghasimi 1 , Simon A. Bretschneider 1 , Wei Huang 1 , Katharina Landfester 1 , Kai A. I. Zhang 1
Affiliation  

Bye bye palladium. Kai A. I. Zhang and co‐workers develope a palladium‐free and photocatalytic Stille‐type coupling reaction of aryl iodides and aryl stannanes by a conjugated microporous polymer‐based photocatalyst under visible light irradiation at room temperature in article number 1700101. Via the aryl radical‐mediated reaction pathway, the light‐promoted coupling reaction using a pure organic photocatalyst offers a simple, sustainable, and more economic aromatic CC bond formation mechanism.
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中文翻译:

偶联反应:共轭微孔聚合物,用于无钯,可见光促进的光催化斯蒂勒型偶联反应(Adv。Sci。8/2017)

再见钯。Kai AI Zhang及其同事在室温下在可见光照射下,通过共轭微孔聚合物基光催化剂开发了无钯且光催化的Stille型偶合反应,该共轭碘化物与芳基锡烷在室温下可见,编号为1700101。介导的反应途径中,使用纯有机光催化剂的光促进偶联反应提供了一种简单,可持续且更经济的芳族CC键形成机理。
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更新日期:2017-08-22
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