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An Update on Isocyanide-Based Multicomponent Reactions in Polymer Science
Topics in Current Chemistry ( IF 8.6 ) Pub Date : 2017-06-12 , DOI: 10.1007/s41061-017-0153-4
Audrey Llevot , Andreas C. Boukis , Stefan Oelmann , Katharina Wetzel , Michael A. R. Meier

Developments and progress in polymer science are often inspired by organic chemistry. In recent years, multicomponent reactions—especially the Passerini and Ugi reactions—have become very important tools for macromolecular design, mainly due to their modular character. In this review, the versatility of the Passerini and Ugi reactions in polymer science is highlighted by discussing recent examples of their use for monomer synthesis, as polymerization techniques, and for postpolymerization modification, as well as their suitability for architecture control, sequence control, and sequence definition.



中文翻译:

高分子科学中基于异氰化物的多组分反应的最新进展

高分子科学的发展与进步通常受到有机化学的启发。近年来,多组分反应(尤其是Passerini和Ugi反应)已成为用于高分子设计的非常重要的工具,这主要是由于它们具有模块化特性。在这篇综述中,通过讨论它们在单体合成,聚合技术和后聚合修饰中的最新应用实例以及它们在结构控制,序列控制和适用性方面的适用性,突出说明了聚合物科学中Passerini和Ugi反应的多功能性。序列定义。

更新日期:2017-06-12
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