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Electroanalytical Ventures at Nanoscale Interfaces Between Immiscible Liquids
Annual Review of Analytical Chemistry ( IF 8 ) Pub Date : 2016-06-15 00:00:00 , DOI: 10.1146/annurev-anchem-071015-041415
Damien W.M. Arrigan 1 , Yang Liu 1
Affiliation  

Ion transfer at the interface between immiscible electrolyte solutions offers many benefits to analytical chemistry, including the ability to detect nonredox active ionized analytes, to detect ions whose redox electrochemistry is accompanied by complications, and to separate ions based on electrocontrolled partition. Nanoscale miniaturization of such interfaces brings the benefits of enhanced mass transport, which in turn leads to improved analytical performance in areas such as sensitivity and limits of detection. This review discusses the development of such nanoscale interfaces between immiscible liquids and examines the analytical advances that have been made to date, including prospects for trace detection of ion concentrations.

中文翻译:


在不混溶液体之间形成纳米级界面的电分析企业

在不混溶的电解质溶液之间的界面处的离子转移为分析化学提供了许多好处,包括检测非氧化还原活性离子化分析物的能力,检测氧化还原电化学伴随着并发症的离子的能力以及基于电控分配分离离子的能力。此类接口的纳米级微型化带来了增强的质量传输的好处,进而提高了灵敏度和检测限等领域的分析性能。这篇综述讨论了不混溶液体之间这种纳米级界面的发展,并考察了迄今为止取得的分析进展,包括离子浓度痕量检测的前景。

更新日期:2016-06-15
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