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Facile synthesis of Co/La-MOF/Ti3C2Tx nanocomposite for electromagnetic wave absorption
Journal of Alloys and Compounds ( IF 6.2 ) Pub Date : 2023-06-02 , DOI: 10.1016/j.jallcom.2023.170829
Yixi Xu , Yufei Huang , Jia Zhao , Xuhui Han , Chunpeng Chai , Huiling Ma

Two-dimensional nanomaterial MXene Ti3C2Tx with excellent electrical conductivity has received extensive attention in the electromagnetic wave (EMW) absorption field. However, the excessively high permittivity of Ti3C2Tx is not conducive to impedance matching and the absorption of EMW. Considering the low permittivity and mesoporous structure of MOF, in this work, Co/La-MOF were in situ growth on the surfaces of Ti3C2Tx by a facile co-solvothermal method. The obtained Co/La-MOF anchored on Ti3C2Tx (Co/La-MOF/Ti3C2Tx) composite exhibits low density with excellent EMW absorption performance. Co/La-MOF/Ti3C2Tx-2 (Co2+/La3+ mass ratio of 16:3) shows the minimum reflection loss of -44.15 dB at 4.00 GHz with the effective absorption bandwidth of 3.67 GHz in the frequency range of 14.03-17.70 GHz under 1.3 mm. In addition, the electromagnetic absorption mechanism of Co/La-MOF/Ti3C2Tx was also investigated. It provides an effective strategy for the preparation of a novel absorber with high EMW absorbing performance.



中文翻译:

用于电磁波吸收的 Co/La-MOF/Ti3C2TX 纳米复合材料的简易合成

具有优异导电性的二维纳米材料MXene Ti 3 C 2 T x在电磁波(EMW)吸收领域受到广泛关注。但是Ti 3 C 2 T x过高的介电常数不利于阻抗匹配和EMW的吸收。考虑到 MOF 的低介电常数和介孔结构,在这项工作中,Co/La-MOF通过简便的共溶剂热法在 Ti 3 C 2 T x表面原位生长获得的 Co/La-MOF 锚定在 Ti 3 C 2 T x(Co/La-MOF/Ti 3 C 2 T x )复合材料具有低密度和优异的EMW吸收性能。Co/La-MOF/Ti 3 C 2 T x -2(Co 2+ /La 3+质量比为 16:3) 在 4.00 GHz 时的最小反射损耗为 -44.15 dB  ,有效吸收带宽为 3.67  GHz 1.3 毫米以下的频率范围为 14.03-17.70  GHz  。此外,Co/La-MOF/Ti 3 C 2 T x的电磁吸收机制也被调查了。它为制备具有高电磁波吸收性能的新型吸收体提供了有效的策略。

更新日期:2023-06-02
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