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Fe0.64Ni0.36@C and Mo2C@C heterostructures embedded in N−doped carbons as microwave absorbers
Journal of Alloys and Compounds ( IF 6.2 ) Pub Date : 2023-06-01 , DOI: 10.1016/j.jallcom.2023.170820
Liang Chen , Jing Sui , Geoffrey I.N. Waterhouse , Zhiming Zhang , Liangmin Yu

Multi−component absorbers can improve microwave absorption performance by incorporating multiple loss mechanisms. However, many multi−component absorbers containing magnetic metal-based nanomaterials are unstable, owing to aggregation and oxidation of metal nanomaterials. In this work, (Fe0.64Ni0.36@C/Mo2C@C)@N−C composites were prepared by mixing nickel molybdate, potassium ferricyanide, and dopamine to form a precursor which was subsequently carbonized. The Fe0.64Ni0.36 and Mo2C nanoparticles in the composites were stabilized by a thin graphitic carbon coating and uniformly dispersed throughout the N-C matrix. This unique structure provided abundant interfaces for microwave absorption, whilst also effectively inhibiting the aggregation and oxidation of the metal-containing phases. One of the prepared composites, (Fe0.64Ni0.36@C/Mo2C@C)@N−C−3, possessed excellent microwave absorption properties, evidenced by a wide effective absorption bandwidth (EAB) of 5.7 GHz (11.9−17.6 GHz) at 2.0 mm thickness, and the minimum reflection loss value (RLmin) of −37.5 dB at 11.92 GHz and 2.5 mm thickness (at a filling amount of 16.7%).



中文翻译:

嵌入 N-掺杂碳中的 Fe0.64Ni0.36@C 和 Mo2C@C 异质结构作为微波吸收剂

多组分吸收器可以通过结合多种损耗机制来提高微波吸收性能。然而,由于金属纳米材料的聚集和氧化,许多含有磁性金属基纳米材料的多组分吸收剂不稳定。在这项工作中,(Fe 0.64 Ni 0.36 @C/Mo 2 C@C)@NC 复合材料通过混合钼酸镍、铁氰化钾和多巴胺形成前体,随后将其碳化来制备。Fe 0.64 Ni 0.36和 Mo 2复合材料中的 C 纳米颗粒通过薄石墨碳涂层稳定,并均匀分散在整个 NC 基质中。这种独特的结构为微波吸收提供了丰富的界面,同时也有效地抑制了含金属相的聚集和氧化。其中一种制备的复合材料 (Fe 0.64 Ni 0.36 @C/Mo 2 C@C)@N−C−3 具有出色的微波吸收性能,有效吸收带宽 (EAB) 高达 5.7  GHz (11.9−17.6)  GHz) 在 2.0  mm 厚度下,最小反射损耗值 (RL min ) 在 11.92  GHz 和 2.5  mm 厚度(填充量为 16.7%)下为 −37.5 dB。

更新日期:2023-06-02
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