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Dihydrogen and Ethylene Activation by a Sterically Distorted Distibene
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2023-06-02 , DOI: 10.1002/anie.202302071
Yue Pang 1 , Markus Leutzsch 1 , Nils Nöthling 1 , Josep Cornella 1
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Herein, we report a hindered and highly distorted distibene complex capable of reacting with H2 and ethylene. NMR studies point to a feasible dissociation of the dimeric species into a fleeting stibinidene intermediate, which rapidly engages in reactivity. Such transition-metal-like reactivity for SbI compounds provides crucial understanding towards the putative Sb redox catalysis.

中文翻译:

空间扭曲的二苯乙烯活化氢气和乙烯

在此,我们报道了一种受阻且高度扭曲的二苯乙烯配合物,能够与H 2和乙烯反应。核磁共振研究表明,二聚体可以解离为短暂的二亚联苯中间体,该中间体迅速参与反应。Sb I化合物的这种类似过渡金属的反应性为推定的 Sb 氧化还原催化提供了重要的理解。
更新日期:2023-06-02
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