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Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds Nat. Catal. (IF 37.8) Pub Date : 2024-03-11 Congjun Yu, Zining Zhang, Guangbin Dong
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A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis Nat. Catal. (IF 37.8) Pub Date : 2024-03-11 Bingxing Zhang, Jianmei Wang, Guimei Liu, Catherine M. Weiss, Danqing Liu, Yaping Chen, Lixue Xia, Peng Zhou, Mingxia Gao, Yongfeng Liu, Jian Chen, Yushan Yan, Minhua Shao, Hongge Pan, Wenping Sun
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Lithium-mediated nitrogen reduction to ammonia via the catalytic solid–electrolyte interphase Nat. Catal. (IF 37.8) Pub Date : 2024-03-11 Wesley Chang, Anukta Jain, Fateme Rezaie, Karthish Manthiram
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Biocatalytic polymer synthesis with β-amino acids Nat. Catal. (IF 37.8) Pub Date : 2024-02-27 Jan-Stefan Völler
Now, Jason W. Chin and colleagues report tRNA display as a ribosome-independent approach to evolve orthogonal synthetases for tRNA acylation with non-canonical monomers in Escherichia coli cells. Isolated orthogonal tRNAs that were successfully acylated in vivo by the orthogonal synthetase were labelled with a biotin moiety for pulldown, whereas non-acylated orthogonal tRNAs were oxidized and excluded
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Closed-loop optimization Nat. Catal. (IF 37.8) Pub Date : 2024-02-27 Marçal Capdevila-Cortada
Now, Paco Laveille and colleagues combine Bayesian optimization, automated synthesis and high-throughput catalytic experiments in a closed-loop approach to design cost-effective heterogeneous catalysts with high activity and selectivity for the hydrogenation of CO2 to methanol. In their study they considered six metals, namely cerium, cobalt, copper, iron, indium and zinc, potassium as a promoter,
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Just counting ten Nat. Catal. (IF 37.8) Pub Date : 2024-02-27 Chenyu Wang
By analysing the adsorption energies of common atomic adsorbates (for example, O, N, C, H) on various transition metal dopants in SAAs, the team discovered a correlation between the adsorption strength and the valence electron count of both adsorbate and dopant. In particular, they showed that the strongest binding corresponds to a total of ten valence electrons for hydrogen and twelve for p-block
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Resurrecting an ancient coenzyme Q metabolon Nat. Catal. (IF 37.8) Pub Date : 2024-02-27 Kelsey J. Feustel, Catherine F. Clarke
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The quest for correlations Nat. Catal. (IF 37.8) Pub Date : 2024-02-27
Correlating structure and activity is a very important research goal in catalysis. This Editorial reflects on this topic, taking inspiration from examples in the current issue.
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Revisiting the universal principle for the rational design of single-atom electrocatalysts Nat. Catal. (IF 37.8) Pub Date : 2024-02-27 Haoxiang Xu, Daojian Cheng, Dapeng Cao, Xiao Cheng Zeng
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Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase Nat. Catal. (IF 37.8) Pub Date : 2024-02-23 Christopher Fröhlich, H. Adrian Bunzel, Karol Buda, Adrian J. Mulholland, Marc W. van der Kamp, Pål J. Johnsen, Hanna-Kirsti S. Leiros, Nobuhiko Tokuriki
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Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation Nat. Catal. (IF 37.8) Pub Date : 2024-02-23 Tong-De Tan, Juan M. I. Serviano, Xiaohua Luo, Peng-Cheng Qian, Patrick L. Holland, Xinglong Zhang, Ming Joo Koh
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A family of di-glutamate mucin-degrading enzymes that bridges glycan hydrolases and peptidases Nat. Catal. (IF 37.8) Pub Date : 2024-02-23 Yoshiki Narimatsu, Christian Büll, Víctor Taleb, Qinghua Liao, Ismael Compañón, David Sánchez-Navarro, Fabien Durbesson, Renaud Vincentelli, Lars Hansen, Francisco Corzana, Carme Rovira, Bernard Henrissat, Henrik Clausen, Hiren J. Joshi, Ramon Hurtado-Guerrero
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Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer Nat. Catal. (IF 37.8) Pub Date : 2024-02-23 Jun Guo, Qi Xia, Wing Yi Tang, Zekun Li, Xia Wu, Li-Juan Liu, Wai-Pong To, Hui-Xing Shu, Kam-Hung Low, Philip C. Y. Chow, Tsz Woon Benedict Lo, Jian He
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Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides Nat. Catal. (IF 37.8) Pub Date : 2024-02-23 Pengfei Li, Zile Zhu, Chengcheng Guo, Guangsheng Kou, Siyi Wang, Pengfei Xie, Dengke Ma, Tian Feng, Yanwei Wang, Youai Qiu
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Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation Nat. Catal. (IF 37.8) Pub Date : 2024-02-20 Sudip Maiti, Pintu Ghosh, Dineshkumar Raja, Sudev Ghosh, Sagnik Chatterjee, Velayudham Sankar, Sayan Roy, Goutam Kumar Lahiri, Debabrata Maiti
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Metal-free organocatalytic S-formylation of thiols using CO2 Nat. Catal. (IF 37.8) Pub Date : 2024-02-19 Subir Maji, Arpan Das, Madhur Mahesh Bhatt, Swadhin K. Mandal
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Nanoparticle proximity controls selectivity in benzaldehyde hydrogenation Nat. Catal. (IF 37.8) Pub Date : 2024-02-16 Kang Rui Garrick Lim, Selina K. Kaiser, Haichao Wu, Sadhya Garg, Marta Perxés Perich, Jessi E. S. van der Hoeven, Michael Aizenberg, Joanna Aizenberg
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Acid–base chemistry and the economic implication of electrocatalytic carboxylate production in alkaline electrolytes Nat. Catal. (IF 37.8) Pub Date : 2024-02-13 Shariful Kibria Nabil, Mohammed Arshad Muzibur Raghuman, Karthick Kannimuthu, Mohsina Rashid, Hadi Shaker Shiran, Md Golam Kibria, M. A. Khan
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Linkage-engineered donor–acceptor covalent organic frameworks for optimal photosynthesis of hydrogen peroxide from water and air Nat. Catal. (IF 37.8) Pub Date : 2024-02-13 Ruoyang Liu, Yongzhi Chen, Hongde Yu, Miroslav Položij, Yuanyuan Guo, Tze Chien Sum, Thomas Heine, Donglin Jiang
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Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents Nat. Catal. (IF 37.8) Pub Date : 2024-02-13 Antonis M. Messinis, Tristan von Münchow, Max Surke, Lutz Ackermann
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Pickering emulsion droplets and solid microspheres acting synergistically for continuous-flow cascade reactions Nat. Catal. (IF 37.8) Pub Date : 2024-02-13 Ming Zhang, Rammile Ettelaie, Ting Li, Jianqin Yang, Lianlian Dong, Nan Xue, Bernard P. Binks, Fangqin Cheng, Hengquan Yang
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Catalysts made from vapour Nat. Catal. (IF 37.8) Pub Date : 2024-01-29 Matthias Filez, Jolien Dendooven, Christophe Detavernier
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Red light is ‘Go!’ for protein labelling Nat. Catal. (IF 37.8) Pub Date : 2024-01-29 Francesco Zamberlan
Indeed, the group was able to insert p-tolyl(trifluoromethyl) diazo reagents with electron-rich and electron-neutral substituents onto the O–H bond of methanol with photocatalyst [Os(Me4phen)3][Cl]2 (where ‘phen’ is phenanthroline) under deep-red (660 nm) or NIR light (740 nm) — depicted in the image. This is achieved via the formation of the desired carbene upon energy transfer from the excited photocatalyst
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Privileged Brønsted acid organocatalysis Nat. Catal. (IF 37.8) Pub Date : 2024-01-29 Svetlana B. Tsogoeva
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The rise of ab initio surface thermodynamics Nat. Catal. (IF 37.8) Pub Date : 2024-01-29 Taehun Lee, Aloysius Soon
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A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products Nat. Catal. (IF 37.8) Pub Date : 2024-01-29 Jian Li, Xin Mu, Wenyue Dong, Yun Chen, Qianjin Kang, Guang Zhao, Jin Hou, Ramon Gonzalez, Linquan Bai, Yan Feng, Chen Yang, Tiangang Liu, Zaigao Tan
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And yet it rotates! Nat. Catal. (IF 37.8) Pub Date : 2024-01-29 Serhiy Cherevko, Ioannis Katsounaros
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An electrochemical approach for designing thermochemical bimetallic nitrate hydrogenation catalysts Nat. Catal. (IF 37.8) Pub Date : 2024-01-19 Kunal M. Lodaya, Bryan Y. Tang, Ryan P. Bisbey, Sophia Weng, Karl S. Westendorff, Wei Lun Toh, Jaeyune Ryu, Yuriy Román-Leshkov, Yogesh Surendranath
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Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes Nat. Catal. (IF 37.8) Pub Date : 2024-01-17 Quan-Hao Wu, Meng Duan, Yu Chen, Peiyuan Yu, Yong-Bin Wang, Jun Kee Cheng, Shao-Hua Xiang, Kendall N. Houk, Bin Tan
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Acid-stable manganese oxides for proton exchange membrane water electrolysis Nat. Catal. (IF 37.8) Pub Date : 2024-01-17 Shuang Kong, Ailong Li, Jun Long, Kiyohiro Adachi, Daisuke Hashizume, Qike Jiang, Kazuna Fushimi, Hideshi Ooka, Jianping Xiao, Ryuhei Nakamura
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Catalytic synthesis of β-lactam derivatives by carbonylative cycloaddition of acylsilanes with imines via a palladium Fischer-carbene intermediate Nat. Catal. (IF 37.8) Pub Date : 2024-01-15 Tetsuya Inagaki, Takuya Kodama, Mamoru Tobisu
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Direct measurement of the oxygen reduction reaction kinetics on iron phthalocyanine using advanced transient voltammetry Nat. Catal. (IF 37.8) Pub Date : 2024-01-12 Rifael Z. Snitkoff-Sol, Or Rimon, Alan M. Bond, Lior Elbaz
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CO2 fixation into carbon nanofibres using electrochemical–thermochemical tandem catalysis Nat. Catal. (IF 37.8) Pub Date : 2024-01-11 Zhenhua Xie, Erwei Huang, Samay Garg, Sooyeon Hwang, Ping Liu, Jingguang G. Chen
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Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion Nat. Catal. (IF 37.8) Pub Date : 2024-01-09 Fu-Peng Wu, Chetan C. Chintawar, Remy Lalisse, Poulami Mukherjee, Subhabrata Dutta, Jasper Tyler, Constantin G. Daniliuc, Osvaldo Gutierrez, Frank Glorius
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Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane Nat. Catal. (IF 37.8) Pub Date : 2024-01-09 Luis Sandoval-Diaz, Daniel Cruz, Maurits Vuijk, Gianmarco Ducci, Michael Hävecker, Wulyu Jiang, Milivoj Plodinec, Adnan Hammud, Danail Ivanov, Thomas Götsch, Karsten Reuter, Robert Schlögl, Christoph Scheurer, Axel Knop-Gericke, Thomas Lunkenbein
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Electrolyte-assisted polarization leading to enhanced charge separation and solar-to-hydrogen conversion efficiency of seawater splitting Nat. Catal. (IF 37.8) Pub Date : 2024-01-04 Yiyang Li, Hui Zhou, Songhua Cai, Dharmalingam Prabhakaran, Wentian Niu, Alexander Large, Georg Held, Robert A. Taylor, Xin-Ping Wu, Shik Chi Edman Tsang
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Selective deoxygenation of biomass-derived carbonyl compounds on Zn via electrochemical Clemmensen reduction Nat. Catal. (IF 37.8) Pub Date : 2024-01-04 Xin Yuan, Kwanpyung Lee, Jonah B. Eisenberg, J. R. Schmidt, Kyoung-Shin Choi
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In vitro construction of the COQ metabolon unveils the molecular determinants of coenzyme Q biosynthesis Nat. Catal. (IF 37.8) Pub Date : 2024-01-03 Callum R. Nicoll, Laura Alvigini, Andrea Gottinger, Domiziana Cecchini, Barbara Mannucci, Federica Corana, María Laura Mascotti, Andrea Mattevi
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Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction Nat. Catal. (IF 37.8) Pub Date : 2024-01-03 Jan Vavra, Gaétan P. L. Ramona, Federico Dattila, Attila Kormányos, Tatiana Priamushko, Petru P. Albertini, Anna Loiudice, Serhiy Cherevko, Núria Lopéz, Raffaella Buonsanti
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Interfacial tuning of electrocatalytic Ag surfaces for fragment-based electrophile coupling Nat. Catal. (IF 37.8) Pub Date : 2024-01-02 Qiu-Cheng Chen, Sarah Kress, Rocco Molinelli, Anna Wuttig
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Cascade electrosynthesis of LiTFSI and N-containing analogues via a looped Li–N2 battery Nat. Catal. (IF 37.8) Pub Date : 2024-01-02 Xiang Zhang, Wenping Xiong, Tao Wang, Erchong Chai, Jing Lin, Lanting Huang, Yangyang Feng, Maoxiang Wu, Yaobing Wang
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Motorized catalysis Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Francesco Zamberlan
Catalysis of this reaction proceeds through a four-step cycle consisting of two chemical transformations (ester formation and ester hydrolysis) that occur at different rates depending on the two conformational states of the ratchet. The stochastic exchange between these conformations during the cycle happens at a twofold higher rate than the chemical steps, which become the rate determining steps.
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Divide and conquer towards synthetic autotrophy Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Wei Xiong, Yanhe Ma
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Designer catalytic nanopores meet PET nanoparticles Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Ren Wei, Uwe T. Bornscheuer
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Construction and modular implementation of the THETA cycle for synthetic CO2 fixation Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Shanshan Luo, Christoph Diehl, Hai He, YoungJun Bae, Melanie Klose, Peter Claus, Niña Socorro Cortina, Celia Alvarez Fernandez, Helena Schulz-Mirbach, Richard McLean, Adán Andrés Ramírez Rojas, Daniel Schindler, Nicole Paczia, Tobias J. Erb
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Terpene synthases in giant viruses Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Jan-Stefan Völler
Now, Takaaki Mitsuhashi, Makoto Fujita and colleagues discovered a functional terpene synthase in a giant virus. With the help of bioinformatics tools, three potential terpene synthases were identified, and it was shown that they are phylogenetically distinct from previously described terpene synthases. The researchers decided to focus on the one that contains the conserved DDXXD motif of class I terpene
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Big Al for In Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Marçal Capdevila-Cortada
Now, Emiel Hensen and colleagues at the Eindhoven University of Technology present a series of Al-doped In2O3 catalysts, prepared by flame spray pyrolysis (FSP), to boost methanol productivity from the hydrogenation of CO2. They synthesized Al2O3–In2O3 catalysts with 2, 5, 10 and 20 mol% Al content, as well as a control material with 5 mol% Al prepared via impregnation. Catalytic CO2 hydrogenation
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Modifying Fe–N interaction to boost catalytic performance Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Ulrike I. Kramm, Lior Elbaz
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Cycloaddition with asymmetric photoelectrocatalysis Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Yongsheng Tao, Cheng Huang, Qingquan Lu
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Electrify to decarbonize Nat. Catal. (IF 37.8) Pub Date : 2023-12-20
Electrification offers a means to decarbonize the chemical industry. In this Editorial we reflect on opportunities in the area of catalysis that come with an increasing availability of renewable electricity.
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The why and how of NOx electroreduction to ammonia Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Jason John, Douglas R. MacFarlane, Alexandr N. Simonov
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Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Jung Yoon ‘Timothy’ Kim, Chase Sellers, Shaoyun Hao, Thomas P. Senftle, Haotian Wang
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Current state and future prospects of liquid metal catalysis Nat. Catal. (IF 37.8) Pub Date : 2023-12-20 Syeda Saba Fatima, Karma Zuraiqi, Ali Zavabeti, Vaishnavi Krishnamurthi, Kourosh Kalantar-Zadeh, Ken Chiang, Torben Daeneke
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Enantioselective decarboxylative alkylation using synergistic photoenzymatic catalysis Nat. Catal. (IF 37.8) Pub Date : 2023-12-18 Shang-Zheng Sun, Bryce T. Nicholls, David Bain, Tianzhang Qiao, Claire G. Page, Andrew J. Musser, Todd K. Hyster
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Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation Nat. Catal. (IF 37.8) Pub Date : 2023-12-06 Satyajit Roy, David A. Vargas, Pengchen Ma, Arkajyoti Sengupta, Ledong Zhu, K. N. Houk, Rudi Fasan
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Metabolic engineering of yeast for the production of carbohydrate-derived foods and chemicals from C1–3 molecules Nat. Catal. (IF 37.8) Pub Date : 2023-12-05 Hongting Tang, Lianghuan Wu, Shuyuan Guo, Wenbing Cao, Wenhui Ma, Xiang Wang, Junfeng Shen, Menglin Wang, Qiannan Zhang, Mingtao Huang, Xiaozhou Luo, Jie Zeng, Jay D. Keasling, Tao Yu
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Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts Nat. Catal. (IF 37.8) Pub Date : 2023-12-05 Yachao Zeng, Chenzhao Li, Boyang Li, Jiashun Liang, Michael J. Zachman, David A. Cullen, Raphael P. Hermann, E. Ercan Alp, Barbara Lavina, Stavros Karakalos, Marcos Lucero, Bingzhang Zhang, Maoyu Wang, Zhenxing Feng, Guofeng Wang, Jian Xie, Deborah J. Myers, Jean-Pol Dodelet, Gang Wu
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Plasmonic bimetallic two-dimensional supercrystals for H2 generation Nat. Catal. (IF 37.8) Pub Date : 2023-11-30 Matias Herran, Sabrina Juergensen, Moritz Kessens, Dominik Hoeing, Andrea Köppen, Ana Sousa-Castillo, Wolfgang J. Parak, Holger Lange, Stephanie Reich, Florian Schulz, Emiliano Cortés