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Synthesis of a new 1,2,3-triazoles scaffold using a heterogeneous multifunctional copper photocatalyst for in vitro investigation via click reaction Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-23 Abolfazl Mohammadkhani, Samanesadat Hosseini, Seied Ali Pourmousavi, Akbar Heydari, Mohammad Mahdavi
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The electrocatalytic hydrogen evolution reaction in the presence of a metal-free organic catalyst based on 1,10-phenanthroline: the first example of a reaction proceeding by an intramolecular mechanism Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-23 Alexandr V. Dolganov, Angelina D. Yudina, Tatiana V. Boykova, Ludmila A. Klimaeva, Ekaterina V. Okina, Sergey G. Kostryukov
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Primary amines from alkenes and carbonyl compounds: highly selective hydrogenation of oximes using a homogeneous Ru-catalyst Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-17 Kevin Hares, Hannes W. Wegener, Thomas F. H. Roth, René Reichert, Dieter Vogt, Thomas Seidensticker
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Preparation of an OHCP nanofiber photocatalyst for cross-dehydrogenation coupling reactions Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-15 Xingshun Zhao, Yunshuai Mi, Tingwei Cai, Wanming Chen, Xia Dong, Jinxin He, Qiangqiang Zhao
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Efficient MnFe/Al2O3 catalyst for NH3-SCR of NO at low temperature: the influence of strong interactions between active components and the carrier Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-12 Qian Xu, Zhihong Zheng, Jinjing Luo, Zheng Lai, Jianwen Chen, Jiaxin Shang
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Correction: Continuous flow oxidation of HMF using a supported AuPd-alloy Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-11 Dominik Neukum, Ajai R. Lakshmi Nilayam, Maya E. Ludwig, Athanasios A. Vadarlis, Jan-Dierk Grunwaldt, Erisa Saraçi
Correction for ‘Continuous flow oxidation of HMF using a supported AuPd-alloy’ by Dominik Neukum et al., Catal. Sci. Technol., 2024, https://doi.org/10.1039/d3cy01722b.
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Correction: Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-10 Ina Vollmer, Michael J. F. Jenks, Sebastian Rejman, Florian Meirer, Andrei Gurinov, Marc Baldus, Bert M. Weckhuysen
Correction for ‘Unravelling potential reaction intermediates during catalytic pyrolysis of polypropylene with microscopy and spectroscopy’ by Ina Vollmer et al., Catal. Sci. Technol., 2024, 14, 894–902, https://doi.org/10.1039/d3cy01473h.
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Highly-selective oxidation of benzyl alcohol to benzaldehyde over Co1/NC catalysts Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-10 Fan Xue, Yanle Li, Jingyue Bi, Shangpu Zhuang, Mifen Cui, Zhaoyang Fei, Ziqi Tian, Xu Qiao
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Blue light-driven selective aerobic oxidation of amines by benzothiadiazole metal–organic framework photocatalysis Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-10 Bing Zeng, Yuexin Wang, Fengwei Huang, Kanghui Xiong, Keke Zhang, Xianjun Lang
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Exploration of the active sites on a Rh–In2O3 catalyst for the semi-hydrogenation of acetylene: a theoretical study Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-10 Kaihang Sun, Rui Zou, Chenyang Shen, Chang-jun Liu
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Enhanced catalytic performance for toluene combustion via Ce-doped α-MnO2: efficient balance between toluene adsorption and activation oxidation Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-10 Yongli Dong, Shuo Li, Chaoqun Chen, Weina Song, Xinglong Li, Fan Wang, Lina Ma, Xiaotong Wang, Wei Li
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Preparation of a ZnIn2S4–AlOOH composite for the photocatalytic reduction of CO2 to CO Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-10 Sisi Lin, Xinkui Wang, Xiaoyu Liang, Xinxin Zhang, Min Wang
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Stability and enhanced low-temperature NH3-SCR activity of supported vanadate catalysts in a microwave field Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-09 Liyun Song, Cui Liu, Shuangye Li, Chunyi Bian, Xing Fan, Hong He
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Effect of alkali/alkaline-earth-metal doping on the Co3O4 spinel structure and N2O decomposition Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-09 Bin Kang, Mengfei Guo, Haotian Wu, Xiaonan Guo, Zhaoying Di, Ying Wei, Jingbo Jia, Zhou-jun Wang, Runduo Zhang
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Photocatalytic ethene synthesis from ethane dehydrogenation with high selectivity by ZnO-supported Pt nanoparticles Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-09 Wenyu Guo, Wenwen Shi, Junjian Cai, Fen Wei, Xiahui Lin, Xuefeng Lu, Zhengxin Ding, Yidong Hou, Guigang Zhang, Sibo Wang
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Plasma-engraved Co3O4 nanorods with enriched oxygen vacancies for efficient electrocatalytic ammonia synthesis Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-08 Bingru Lan, Jieying Wan, Chuang Guan, Ji Yang, Na Yang, Jiageng Zheng, Xiaodong Li, Hao Zhang
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Effects of Pd and Co intimacy in Pd-modified Co/TiO2 catalysts for direct CO2 hydrogenation to fuels: the closer not the better Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-08 Canio Scarfiello, Aurélien Durupt, Yann Tison, Doan Pham Minh, Katerina Soulantica, Philippe Serp
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Synthesis of a sacubitril precursor via the construction of one-pot chemoenzymatic cascades Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-07 Long Chen, Ge Qu, Zhiqiang Cai, Bo Yuan, Zhoutong Sun
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Theoretical evidence for the enantioselectivity of Mannich reactions with fluorinated aromatic ketones Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-03 Cheng Peng, Jian Zhang, Yong Wang, Wei Liu
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The role of oxygen vacancies and Zn in isobutene synthesis from ethanol employing Zn, Zr-based catalysts Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Mariana G. S. Pinheiro, Eugenio F. de Souza, Luciano H. Chagas, Priscila C. Zonetti, Guilherme G. Gonzalez, Noemi R. C. Huaman, Odivaldo C. Alves, Liane M. Rossi, Luiz E. P. Borges, Lucia G. Appel
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Dual built-in spontaneous electric fields in an S-scheme heterojunction for enhanced photocatalytic H2O2 production Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Junxian Huang, Haiyang Shi, Xuefei Wang, Ping Wang, Feng Chen, Huogen Yu
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Unique dendritic Bi2S3 with ultrathin nanosheets rich in S vacancy-defects toward promoting highly efficient photothermal CO2 reduction into CO Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Yanjun Zhu, Qiutong Han, He Qu, Yan Shen, Xin Zhou, Zhigang Zou, Yong Zhou
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Designing bifunctional catalysts for the one-pot conversion of CO2 to sustainable marine transportation fuels Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Maciej G. Walerowski, Matthew E. Potter, Elizabeth S. Burke, Stylianos Kyrimis, Lindsay-Marie Armstrong, Robert Raja
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Nickel-embedded zeolite subcrystal catalyst: rapid enhancement of activity and metal impurity resistance in the hydrodesulfurization of 4,6-dimethyldibenzothiophene Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Zhichao Tan, Ke Du, Zhizheng Sheng, Wanyi Li, Huihong Zhu, Lou Gao, He Li, Yi Tang, Yahong Zhang
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Strategically incorporated V in rod-like Ni-MOF as an effective catalyst for the water oxidation reaction Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Krishnendu Bera, Suprobhat Singha Roy, Ragunath Madhu, Aditi De, Pradeep Gudlur, Subrata Kundu
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Carbon-coated FeCoNi nanocatalysts for the electrocatalytic oxygen reduction reaction Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-02 Haitao Huang, Chengcheng Zhang, Haijin Li, Jianmin Wang, Zhijie Chen, Yitao He, Yongtao Li, Jing Hu, Xiaofang Liu, Xiaolong Deng, Shaochun Shi
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In situ laser-assisted synthesis of MoS2 anchored on 3D porous graphene foam for enhanced alkaline hydrogen generation Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-01 Ling Zhang, Wenxiang Fu, Jie Yang, Junchao Yang, Chuan Zhou, Jiang Zhao, Qibin Huang
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The mechanism of CO2 hydrogenation to CH3OH on MZrOx (M = Ga, Cr) solid-solution catalysts and effects of lattice strain Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-04-01 Huili Lu, Deshuai Yang, Zhao-Xu Chen
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Low-coordination M–N3 active sites with high accessibility and efficiency for electrocatalytic O2 and CO2 reduction Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-28 Shan Wei, Hongbo Wu, Cheng Zhou, Liuyi Pan, Lingzhi Huang, Lina Wang, Zhong Li, Jian Zhang
This review summarizes the methods to construct an efficient M–N3 site-enriched porous structure with enhancement of the electrochemical accessibility. Compared with intact M–N4, the low-coordination M–N3 with defect-regulated geometry and high-density electronic structure is elaborated based on the recent progress of various electron beam-based techniques. The catalytic mechanism and the underlying
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Enzymatic cascade of DERA and ADH for lactone synthesis Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-28 Eman Abdelraheem, Robin Kuijpers, Peter-Leon Hagedoorn, Frank Hollmann, Ulf Hanefeld
This study presents a three-step one pot enzymatic cascade for the synthesis of a δ-lactone. Utilising acetaldehyde, combining 2-deoxyribose-5-phosphate aldolase (DERA) with an alcohol dehydrogenase (ADH) and a cofactor regeneration system this δ-lactone is synthesised with the same stereochemistry as the statin side chain precursor. The initial stage in this cascade involves the double aldol reaction
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Electrocatalytic synthesis of hydrogen peroxide based on multi-doped carbon-based nanocatalyst Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-28 Peng Hu, Qijing Zhang, Xiaodong Lu, Zihao Zuo
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In situ use of photocatalytically produced H2O2 for Fenton degradation of organic pollutants Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-28 Uttam Kumar, Anshu Shrivastava, Indrajit Sinha
Recent years have seen increased research on green H2O2 production by photocatalysis. Though the H2O2 formation by photocatalysis is still at a dilute level, it is sufficient to degrade a given organic pollutant by a photo-Fenton process. The in situ Fenton process avoids the costs of H2O2 storage and transportation and uses it more efficiently. The present review is on the in situ Fenton use of the
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Enhanced catalytic oxidation of toluene over amorphous cubic structured manganese oxide-based catalysts promoted by functionally designed Co–Fe nanowires Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-28 Jing Wang, Zhijun Wu, Jinggang Zhao, Ming Sun, Xiaoxun Ma, Abuliti Abudula, Guoqing Guan
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Nickel-catalyzed tandem conversion of paraformaldehyde : methanol to hydrogen and formate/chemo- and stereoselective hydrogenation of alkynes under neutral conditions Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-28 Murugan Subaramanian, Subarna Sukanya Padhy, Chandrakanth Gouda, Tamal Das, Kumar Vanka, Ekambaram Balaraman
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Sulfur substitution in Fe-MOF-74: implications for electrocatalytic CO2 and CO reduction from an ab initio perspective Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-26 Gavin A. McCarver, Taner Yildirim, Wei Zhou
Employing first-principles methods, we investigated the electrocatalytic reduction of CO2 and CO on two Fe-based MOFs: Fe2DOBDC and Fe2DSBDC. Our primary objective was to discern the impact of substituting S atoms into the framework while maintaining the topological structure. We anticipated significant changes in reduction reactions due to differences in chemical properties such as electronegativity
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Valence-to-core X-ray emission spectroscopy to resolve the size-dependent valence electronic structure of Pt nanoparticles Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-26 David P. Dean, Gaurav S. Deshmukh, Christopher K. Russell, Kuixin Zhu, Christina W. Li, Jeffrey P. Greeley, Denis Leshchev, Eli Stavitski, Jeffrey T. Miller
X-ray characterization of catalyst materials using synchrotron radiation has become more widely available to the scientific community in recent decades. Techniques such as X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) have enabled in situ and in operando studies of dilute catalyst sites for heterogeneous catalyst materials in order to obtain information about local
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Molten multi-phase catalytic system comprising Li–Zn alloy and LiCl–KCl salt for nitrogen fixation and ammonia synthesis at ambient pressure Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-26 Xian Meng, Jian Liu, Zujian Tang, Bingxu Xi, Pu Yan, Xingran Wang, Kecheng Cao, Bo Yang, Xiaofei Guan
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Palladium nanoparticle deposition on spherical carbon supports for heterogeneous catalysis in continuous flow Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-26 Sarah L. Boyall, Phoebe Berman, Anthony Griffiths, Alexander Massey, Thomas Dixon, Thomas Shaw, Joanna Miller, Jonathan P. White, Robert Menzel, Kevin Leslie, Graeme Clemens, Frans L. Muller, Richard A. Bourne, Thomas W. Chamberlain
Heterogeneous catalysis is widely exploited by the chemical industry, both in batch reactors and in continuous flow, the latter via the use of packed bed reactors. Unfortunately, the transfer of commercially available heterogeneous catalysts to high pressure flow systems is often difficult, with challenges such as catalyst deactivation through metal leaching, and the crushing of pelleted supports.
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Synergistic effect and coordination environment tuned water-gas shift reaction on MoS2 catalyst Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-25 Hai-Yan Su, Wenbo Liao, Keju Sun
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Photocatalytic hydrogenation of acetophenone over Pd–TiO2 using saccharides as hydrogen sources Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-22 Takahiro Oto, Kazuma Ikeuchi, Kosuke Tanaka, Ayumu Onda, Kazuya Imamura
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Novel hierarchical porous Fe2O3@GA composites for solar-Fenton catalysis of dyes Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-21 Xiaomei Li, Jun Qin, Xiao Zhang, Yu Zhang, Zhixiong Liu, Jianfeng Jia, Haishun Wu, Feng Feng, Yunfeng Bai
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Novel-ordered hierarchical ZSM-5 zeolite with interconnected macro–meso–microporosity for the enhanced methanol to aromatics reaction Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-21 Youhe Wang, Tingting Li, Yuqing Ouyang, Jie Zhong, Yu Zhang, Xiaoyun Xiong, Qingxun Hu, Jiacheng Deng, Hongman Sun, Zifeng Yan
The methanol to aromatics (MTA) process is an attractive non-petroleum route to produce high-value aromatics but suffers from a high rate of carbon deposition and deactivation and relatively low BTX selectivity. Herein, we first prepared a three-dimensional ordered macro–mesoporous carbon material (3DOMmC) with a network structure by dropping-suction filtration. Then the obtained 3DOMmC was utilized
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One-pot synthesis of an ultrafine Cu2O nanocrystal/porous polymer heterostructure for photocatalytic hydrogen production Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-21 Qianru Wu, Rui Ma, Yao Wang, Juan Li, Huiwen Xue, Zhixuan Zhang, Linhan Xu, Hongbing Fu, Li-Zhu Wu, Xu-Bing Li, Huaping Wang
Owing to the high surface energy of nano-sized materials, the controllable synthesis of ultrafine and uniform cuprous oxide (Cu2O) nanocrystals (NCs), which show intrinsic advantages in photochemical conversion, still remains a challenge. Herein, by subtly optimizing reaction conditions and designing organic monomers, we successfully synthesize uniformly-sized and well-dispersed Cu2O NCs (ca. 2.7 nm)
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Photocatalytic activity of Rose Bengal encapsulated in zeolitic imidazolate framework-8 (RB@ZIF-8): an innovative approach for the one pot synthesis of highly functionalized tetrahydropyridines and study of their anti-tubercular activity Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-20 Munmee Goswami, Pooja Paul, Chayan Pandya, Ridahunlang Nongkhlaw, Arup Dutta, Jyothi Kumari, Dharmarajan Sriram, Akella Sivaramakrishna, Rishanlang Nongkhlaw
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Construction of intimate Lewis acid and basic sites on an Al2O3–NC composite catalyst with enhanced performance in transfer hydrogenation of cinnamaldehyde Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-20 Peng Zhang, Lele Bai, Yao Wang, Zhichao Sun, Ying-Ya Liu, Anjie Wang
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Catalytic removal of soot particles over potassium glasses – the effect of doping with aliovalent redox metals Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-19 Piotr Legutko, Michał Dziadek, Gabriela Grzybek, Mateusz Marzec, Emilia Jarosz, Marek Michalik, Marco Piumetti, Katarzyna Cholewa-Kowalska, Debora Fino, Andrzej Adamski
Low-cost, noble metal-free and environmentally friendly potassium glasses constitute a new class of promising catalysts for soot combustion. The effect of doping of potassium silicate glasses with aliovalent metals of prominent redox properties (Mn, Fe, Co, Ni, Cu, Ce) on their catalytic performance in soot combustion was investigated. A series of glasses were synthesized by the melt-quenching method
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Synthesis of amine derivatives from furoin and furil over a Ru/Al2O3 catalyst Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-19 Li Gao, Massimo Delle Piane, Marta Corno, Fan Jiang, Robert Raja, M. Pera-Titus
The direct/reductive amination of carbohydrate-based furoin and furil with NH3/H2 was investigated to access amine derivatives. In the sole presence of NH3, cyclic amines, i.e. 2,3,5,6-tetra(furan-2-yl)pyrazine and 2,2′-bipyridine-3,3′-diol, were generated as the main products from furoin and furil, respectively. Over Ru/Al2O3 under NH3/H2, 2-amino-1,2-di(furan-2-yl)ethan-1-ol (i.e. alcohol–amine)
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Low-temperature direct decomposition of NO over Rh/NC-MnFe catalyst: activity, stability and mechanism Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-19 Xiao Tan, Suitao Qi, Guangxu Cheng, Chunhai Yi, Bolun Yang
As the ideal NO removal technology, the biggest challenge associated with the direct catalytic decomposition of NO is the development of highly active deNOx catalysts at low temperatures. Herein, a composite metal catalyst, Rh(0.2)/NC-MnFe, was prepared via impregnation for the low-temperature direct decomposition of NO, which exhibited 99.6% NO conversion and 63% N2 selectivity at 150 °C, and nearly
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Progress in Cu-based electrocatalysts for electrochemical CO2 reduction to C2+ products Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-19 Shaoying Cui, Siqi Li, Renzhi Deng, Lixin Wei, Shucheng Yang, Shiwei Dai, Fanan Wang, Song Liu, Yanqiang Huang
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Low temperature CO oxidation over Rh supported on N-doped carbon Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-18 Colby A. Whitcomb, Anukriti Shrestha, Christopher Paolucci, Robert J. Davis
Some isolated transition metals supported on nitrogen-doped carbon (M–N–C) are effective catalysts for reactions involving O2, including low temperature CO oxidation. In this work, screening of various M–N–C materials using quantum chemical calculations showed that group 9 transition metals (Co, Rh, and Ir) in nitrogen-doped carbon have similar binding affinities for CO and O2 and were able to form
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A diacetylene covalent organic framework through a one-step two-electron O2 reduction pathway for efficient photosynthesis of H2O2 Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-18 Pengken Li, Hui Zhao, Rong Ji, Wenwen Chi, Xinyu Sun, Yuming Dong, Yongfa Zhu
A one-step two-electron oxygen reduction pathway is crucial for the stable and efficient photosynthesis of hydrogen peroxide. However, the lower oxygen adsorption and activation capacity significantly restrict the ability of the one-step two-electron oxygen reduction pathway. In this work, a covalent organic framework containing a diacetylene unit (COF-Tfp-BDDA) as an efficient oxygen reduction active
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Comprehensive enhancement in electrocatalytic oxygen evolution performance of nickel and cobalt complexes derived from π-conjugated N-heterocyclic carbene ligands through carbon composite strategy Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-18 Monica Vijayakumar, Zhoveta Yhobu, Jan Grzegorz Małecki, Dodahhali H. Nagaraju, Rangappa S. Keri, Srinivasa Budagumpi
Electrocatalysis for oxygen evolution reaction (OER) amidst various advanced technologies for sustainable, clean and highly efficient energy generation plays a key role. In this study, we report nickel (6 and 7) and cobalt (8 and 9) complexes of N-heterocyclic carbene (NHC) ligands to obtain molecular electrocatalysts for OER application. The corresponding triazolium bromide salts (4 and 5) and complexes
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Molecular field analysis in half-titanocene complexes: computational study towards data-driven in silico optimization of single-site olefin polymerization catalysts Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-18 Shigeru Yamaguchi, Takahiro Kikuchi, Kenichi Tanaka, Ikuko Takamiya
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Breaking the activity and stability bottlenecks for acid hydrogen evolution by strong metal–support interaction between Pt nanoparticles and amorphous MoOx Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-15 Bo Ning, Zhen-Feng Huang, Chengxiang Shi, Lun Pan, Ruijie Gao, Xiangwen Zhang, Ji-Jun Zou
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Effect of Ni content on Cu–Mn/ZrO2 catalysts for methanol synthesis from CO2 hydrogenation Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-15 Hengbi Zhang, Jinhai Yang, Shiwei Wang, Ning Zhao, Fukui Xiao, Yanhong Wang
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Novel Mn–Bi–S hybrid mesoporous nanosheets as an efficient electrocatalyst for nitrogen reduction reaction Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-14 Yining Ban, Zizai Ma, Zihao Wan, Hefeng Yuan, Xiaoguang Wang
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Palladium-decorated SiX (X = N, P, As, Sb, Bi) catalysts for hydrogen evolution Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-14 Trilokchand L. Kumavat, Radha N Somaiya, Yogesh Sonvane
Developing single atom catalysts (SAC) is a promising and useful strategy for designing highly efficient and low-cost photo- or electrocatalysts that are active towards hydrogen evolution reaction (HER). Herein, we have explored the structural, electronic and HER catalytic activity of Pd-decorated SiX (X = N, P, As, Sb and Bi) SACs using density-functional theory calculations. A strong interaction
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Engineering of halohydrin dehalogenases for the regio- and stereoselective synthesis of (S)-4-aryl-2-oxazolidinones Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-13 Jinsong Song, Chuanhua Zhou, Xi Chen, Yang Gu, Feng Xue, Qiaqing Wu, Dunming Zhu
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Activation of alkyl hydroperoxides by manganese complexes of tmtacn for initiation of radical polymerisation of alkenes Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-13 Linda E. Eijsink, Andy S. Sardjan, Esther G. Sinnema, Hugo den Besten, Yanrong Zhang, Ronald Hage, Keimpe J. van den Berg, Jitte Flapper, Ben L. Feringa, Wesley R. Browne
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Hydrogenolysis of isosorbide to diols and triols over a heterogeneous SiO2-supported Rh catalyst Catal. Sci. Technol. (IF 5.0) Pub Date : 2024-03-13 Pengru Chen, Wataru Onodera, Masato Akatsuka, Yusuke Kita, Masazumi Tamura