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Constructing magnetic catalysts with in-situ solid-liquid interfacial photo-Fenton-like reaction over Ag3PO4@NiFe2O4 composites
Applied Catalysis B: Environment and Energy ( IF 22.1 ) Pub Date : 2017-11-16 , DOI: 10.1016/j.apcatb.2017.11.045
Shuquan Huang , Yuanguo Xu , Ting Zhou , Meng Xie , Yun Ma , Qingqing Liu , Liquan Jing , Hui Xu , Huaming Li

A high-performance photocatalyst should be superior not only in light absorption and charge transfer but also surface catalytic reaction. Here we report a green and simple strategy for evenly decorating Ag3PO4 particles using magnetic NiFe2O4 nanoparticles (NPs). The NiFe2O4 NPs could act as a magnetic support material for recycling the photocatalysts, as well as in situ catalytically decompose the H2O2 produced on the surface of Ag3PO4 into O2 and OH radicals via a photo-Fenton process. The catalytic decomposition of H2O2 could produce strong oxidative capacity O2 and OH radicals for the organic pollutants degradation and reduce host semiconductor holes (h+(Ag3PO4)) consumption by these produced H2O2. Thus, the photocatalytic activities of Ag3PO4@NiFe2O4 composites were greatly enhanced. Taking the photocatalytic degradation of Methyl orange (MO), hardly decomposed colorless phenol compounds bisphenol A (BPA) and killing Escherichia coli (E. coli) as mode photocatalytic reactions, this system exhibited superior photocatalytic performances than that of pristine Ag3PO4. Electron spin resonance (ESR) spectroscopy and sacrificial-reagent incorporated photocatalytic characterizations indicated that the in situ eliminating/active decomposition of H2O2 produced by Ag3PO4 was the main reason for the enhanced photocatalytic activities.



中文翻译:

Ag 3 PO 4 @NiFe 2 O 4复合材料上原位固液界面光Fenton样反应制备磁性催化剂

高性能的光催化剂不仅在光吸收和电荷转移方面,而且在表面催化反应方面也应优越。在这里,我们报告了一种使用磁性NiFe 2 O 4纳米颗粒(NPs)均匀装饰Ag 3 PO 4颗粒的绿色简单策略。所述的NiFe 2周ö 4的NP可以作为用于催化再循环光催化剂,以及原位分解为H的磁性载体材料2 ö 2 Ag的表面上产生3 PO 4制成O 2 -和经由光致OH自由基Fenton过程。H的催化分解2 ö 2可以产生强烈的氧化能力ö 2 -OH自由基的有机污染物的降解和减少主机半导体孔H+一个G3PØ4由这些产生的H 2 O 2消耗。因此,大大提高了Ag 3 PO 4 @NiFe 2 O 4复合材料的光催化活性。以甲基橙(MO)的光催化降解,无色酚类化合物双酚A(BPA)几乎不分解并杀死大肠杆菌(E. coli)为模式光催化反应,该系统显示出比原始Ag 3 PO 4更好的光催化性能。电子自旋共振(ESR)光谱和牺牲试剂结合的光催化特性表明,H 2的原位消除/活性分解Ag 3 PO 4产生的O 2是增强光催化活性的主要原因。

更新日期:2017-11-16
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