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A Ni(salen)-Based Metal–Organic Framework: Synthesis, Structure, and Catalytic Performance for CO2 Cycloaddition with Epoxides
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2017-11-17 04:25:52 , DOI: 10.1002/ejic.201700871
Yamei Fan 1 , Jiawei Li 1 , Yanwei Ren 1 , Huanfeng Jiang 1
Affiliation  

A three-dimensional chiral metal–organic framework based on a new enantiopure tetracarboxyl-functionalized metallosalen Ni(H4salen) exhibits high activity and size-dependent selectivity for CO2 cycloaddition with epoxides under relatively mild conditions.

中文翻译:

Ni(salen)基金属有机骨架:环氧合成CO2环加成反应的合成,结构和催化性能

基于新的对映纯四羧基官能化金属losalen Ni(H 4 salen)的三维手性金属-有机骨架,在相对温和的条件下,对环氧化物与CO 2环加成反应表现出高活性和尺寸依赖性。
更新日期:2017-11-17
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