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Blackening of aza-BODIPY analogues by simple dimerization: panchromatic absorption of a pyrrolopyrrole aza-BODIPY dimer†
Materials Chemistry Frontiers ( IF 7 ) Pub Date : 2017-11-17 00:00:00 , DOI: 10.1039/c7qm00438a
Yuto Kage 1, 2, 3, 4, 5 , Shigeki Mori 5, 6, 7, 8 , Marina Ide 2, 5, 9, 10, 11 , Akinori Saeki 2, 5, 9, 10, 11 , Hiroyuki Furuta 1, 2, 3, 4, 5 , Soji Shimizu 1, 2, 3, 4, 5
Affiliation  

Dimerization of the so-called pyrrolopyrrole aza-BODIPY, which is a new class of aza-BODIPY analogues exhibiting intense absorption and emission in the visible (Vis) and near infrared (NIR) region, via a bithienyl linkage led to the creation of a novel black dye with dual emission and panchromatic absorption properties in the Vis/NIR region. The role of the linkage in the dye was unambiguously elucidated by comparison of the optical properties with those of its biphenyl-linked counterpart.

中文翻译:

通过简单的二聚化使aza-BODIPY类似物变黑:吡咯并吡咯aza-BODIPY二聚体的全色吸收

所谓的吡咯并吡咯aza-BODIPY的二聚体是一类新型的aza-BODIPY类似物,通过二噻吩基键合在可见(Vis)和近红外(NIR)区域表现出强烈的吸收和发射,从而导致了在Vis / NIR区域具有双重发射和全色吸收特性的新型黑色染料。通过将光学性质与其联苯基连接的对应物的光学性质进行比较,明确阐明了该键在染料中的作用。
更新日期:2017-11-17
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