Versatile palladium-catalyzed double carbonylation of aryl bromides,Chemical Communications

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Versatile palladium-catalyzed double carbonylation of aryl bromides
Chemical Communications ( IF 4.9 ) Pub Date : 2017-10-18 00:00:00 , DOI: 10.1039/c7cc07412c
Chaoren Shen _{1,

2,

3} , Cornel Fink _{4,

5,

6} , Gabor Laurenczy _{4,

5,

6} , Paul J. Dyson _{4,

5,

6} , Xiao-Feng Wu _{1,

2,

3}

Affiliation

A versatile palladium-catalyzed double carbonylation of aryl bromides has been developed. Using Pd(OAc)₂/BuPAd₂ as the catalyst system and DBU as the base, under relatively low CO pressure, various α-ketoamides were produced in good yields. In order to get insight into the reaction pathway, real time NMR studies were performed as well and a correlated reaction mechanism is been given.

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