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Localized Supramolecular Peptide Self-Assembly Directed by Enzyme-Induced Proton Gradients
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-11-16 04:52:48 , DOI: 10.1002/anie.201709029
Jennifer Rodon Fores 1 , Miguel Leonardo Martinez Mendez 1 , Xiyu Mao 1 , Déborah Wagner 1 , Marc Schmutz 1 , Morgane Rabineau 2, 3 , Philippe Lavalle 2, 3 , Pierre Schaaf 1, 2, 3 , Fouzia Boulmedais 1 , Loïc Jierry 1
Affiliation  

The power of enzymes: A multilayer film including a bi-enzyme reaction system establishes a proton gradient going from the bottom to the top of the film, leading to the localized self-assembly of peptides that underpin a supramolecular hydrogel. This approach constitutes an alternative to an electrode surface to induce pH-sensitive self-assembly processes.

中文翻译:

酶诱导质子梯度指导的局部超分子肽自组装。

酶的力量:包含双酶反应系统的多层膜在膜的底部到顶部建立了质子梯度,从而导致了支持超分子水凝胶的肽的局部自组装。该方法构成了诱导pH敏感的自组装过程的电极表面的替代方法。
更新日期:2017-11-16
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