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Radical polymerization of acrylic monomers: An overview
Progress in Polymer Science ( IF 27.1 ) Pub Date : 2017-11-14 , DOI: 10.1016/j.progpolymsci.2017.11.002
Nicholas Ballard , Jose M. Asua

Since their discovery and development in the 20th century, acrylic polymers have become an integral part of numerous industries and are used in a myriad of applications. As is true for many polymers, the suitability of a particular polyacrylate for a given application comes from its structure, which is determined during its synthesis in the reactor, long before commercial use. Uniquely, the radical polymerization of acrylic monomers is strongly affected by radical transfer events which dictate reaction kinetics and lead to a range of distinct macromolecular structures, a fact that went unknown for many years and continues to generate unexpected results. In this review, we aim to present the current picture of the various competitive processes which occur during polymerization of acrylic monomers, as well as the ongoing issues that hinder our complete comprehension of this complicated monomer family.



中文翻译:

丙烯酸单体的自由基聚合:概述

自20世纪被发现和发展以来,丙烯酸聚合物已成为众多行业不可或缺的一部分,并在众多应用中得到使用。就像许多聚合物一样,特定聚丙烯酸酯对给定应用的适用性来自其结构,而该结构是在其在反应器中合成的过程中确定的,很早就已在商业上使用。独特的是,丙烯酸酯单体的自由基聚合反应受自由基转移事件的强烈影响,自由基转移事件决定了反应动力学并导致一系列独特的大分子结构,这一事实多年来一直未知,并继续产生意想不到的结果。在这篇评论中,我们旨在介绍丙烯酸单体聚合过程中发生的各种竞争过程的最新情况,

更新日期:2017-11-14
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