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Self-assembly and photocatalytic H2 evolution activity of two nanoscale polytantalotungstates based on unprecedented {Cr3Ta6} and {Cr4Ta12} clusters
Journal of Materials Chemistry A ( IF 11.9 ) Pub Date : 2017-10-19 00:00:00 , DOI: 10.1039/c7ta06822k Peng Huang 1, 2, 3, 4, 5 , Xiao-Jun Wang 1, 2, 3, 4, 5 , Jiao-Jiao Qi 1, 2, 3, 4, 5 , Xin-Long Wang 6, 7, 8, 9, 10 , Min Huang 1, 2, 3, 4, 5 , Hai-Yang Wu 1, 2, 3, 4, 5 , Chao Qin 6, 7, 8, 9, 10 , Zhong-Min Su 6, 7, 8, 9, 10
Journal of Materials Chemistry A ( IF 11.9 ) Pub Date : 2017-10-19 00:00:00 , DOI: 10.1039/c7ta06822k Peng Huang 1, 2, 3, 4, 5 , Xiao-Jun Wang 1, 2, 3, 4, 5 , Jiao-Jiao Qi 1, 2, 3, 4, 5 , Xin-Long Wang 6, 7, 8, 9, 10 , Min Huang 1, 2, 3, 4, 5 , Hai-Yang Wu 1, 2, 3, 4, 5 , Chao Qin 6, 7, 8, 9, 10 , Zhong-Min Su 6, 7, 8, 9, 10
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Two nanoscale polytantalotungstates (POTTs), Cs5K4{Cr3[Ta3P2W15O62]2(H2O)12}·15H2O (1) and Cs8.5K8Na2H5.5{Cr4[Ta3P2W15O62]4(H2O)12}·53H2O (2), based on unprecedented {Cr3Ta6} and {Cr4Ta12} clusters, respectively, were hydrothermally synthesized. A photocatalytic study revealed that 1 and 2 exhibit significant photocatalytic water splitting activities.
中文翻译：
基于史无前例的{Cr 3 Ta 6 }和{Cr 4 Ta 12 }团簇的两种纳米级多钽五钨酸盐的自组装和光催化H 2析出活性
两种纳米级多钽钽酸盐（POTTs），Cs 5 K 4 {Cr 3 [Ta 3 P 2 W 15 O 62 ] 2（H 2 O）12 }·15H 2 O（1）和Cs 8.5 K 8 Na 2 H 5.5 {Cr 4 [Ta 3 P 2 W 15 O 62 ] 4（H 2 O）12 }·53H 2 O（2），基于前所未有的{Cr水热合成了3个Ta 6 }和{Cr 4 Ta 12 }团簇。光催化研究表明1和2表现出显着的光催化水分解活性。
更新日期：2017-11-14
中文翻译：
基于史无前例的{Cr 3 Ta 6 }和{Cr 4 Ta 12 }团簇的两种纳米级多钽五钨酸盐的自组装和光催化H 2析出活性
两种纳米级多钽钽酸盐（POTTs），Cs 5 K 4 {Cr 3 [Ta 3 P 2 W 15 O 62 ] 2（H 2 O）12 }·15H 2 O（1）和Cs 8.5 K 8 Na 2 H 5.5 {Cr 4 [Ta 3 P 2 W 15 O 62 ] 4（H 2 O）12 }·53H 2 O（2），基于前所未有的{Cr水热合成了3个Ta 6 }和{Cr 4 Ta 12 }团簇。光催化研究表明1和2表现出显着的光催化水分解活性。
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