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Plasmonic molybdenum oxide nanosheets supported silver nanocubes for enhanced near-infrared antibacterial activity: Synergism of photothermal effect, silver release and photocatalytic reactions
Applied Catalysis B: Environment and Energy ( IF 22.1 ) Pub Date : 2017-11-11 , DOI: 10.1016/j.apcatb.2017.11.024
Qiaoqiao Yin , Linxiang Tan , Qingqing Lang , Xiaoxia Ke , Lijie Bai , Kaiyan Guo , Ru Qiao , Song Bai

Plasmonic MoO3−x nanosheets supported Ag nanocubes were designed as high-efficient Near-infrared (NIR) light driven antibacterial agent. The as-designed MoO3−x-Ag not only significantly reduces the cost and toxicity of Ag, but also greatly enhances the antibacterial activity towards E. coli and S. aureus in comparison with bare MoO3−x and Ag upon NIR laser irradiation. Three effects are believed to contribute to this enhancement: (1) the plasmonic MoO3−x-Ag exhibits excellent NIR light absorption and photothermal conversion abilities, which help to kill bacteria; (2) NIR light induced heat in MoO3−x also diffuses to Ag nanocubes and triggers the release of more Ag+, leading to bacterial cell death; (3) under NIR light irradiation, hot electrons and holes are generated and separated through MoO3−x-Ag interface, which produces reactive species for the oxidation of out membrane of bacteria. The synergism of NIR light driven photothermal effect, silver release and photocatalytic reaction makes the designed plasmonic MoO3−x-Ag a promising antibacterial agent for cleaning the microbial contaminated water environment.



中文翻译:

等离子体氧化钼纳米片支持银纳米立方体以增强近红外抗菌活性:光热效应,银释放和光催化反应的协同作用

载有Ag纳米立方体的等离子MoO 3-x纳米片被设计为高效的近红外(NIR)光驱动抗菌剂。与裸露的MoO 3-x和Ag相比,如此设计的MoO 3-x -Ag不仅显着降低了Ag的成本和毒性,而且还大大增强了其对大肠杆菌金黄色葡萄球菌的抗菌活性。相信有三种作用可促进这种增强:(1)等离子体MoO 3-x -Ag具有出色的近红外吸收和光热转换能力,有助于杀死细菌。(2)NIR光在MoO 3-x中感应出的热量还扩散到Ag纳米立方体并触发更多Ag +的释放,导致细菌细胞死亡。(3)在近红外光照射下,通过MoO 3-x -Ag界面产生并分离出热电子和空穴,从而产生反应性种,以氧化细菌的外膜。近红外光驱动的光热效应,银的释放和光催化反应的协同作用使所设计的等离子体MoO 3-x -Ag成为有望用于清洁微生物污染水环境的抗菌剂。

更新日期:2017-11-11
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