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Confining Gold Nanoclusters in Highly Defective Graphitic Layers To Enhance the Methanol Electrooxidation Reaction
ChemCatChem ( IF 4.5 ) Pub Date : 2017-11-08 09:08:43 , DOI: 10.1002/cctc.201700895
Zhe Mao 1, 2 , Haihua Hu 2 , Rui Su 3 , Peizhi Liu 4 , Yixing Li 2 , Wenting Zhang 2 , Xiaoning Zhao 2 , Junjie Guo 4 , Pengfei Guan 3 , Gaowu Qin 2 , Xuefeng Zhang 1, 2
Affiliation  

Good as gold: A Au@C nanocomposite comprising 3–5 nm gold clusters confined within few-layered, highly defective graphitic cages is prepared; this nanocomposite exhibits high catalytic activity and excellent stability for the electrooxidation of methanol. The defective graphitic layers prohibit chemical/thermal coarsening of the gold clusters and also provide effective penetration channels for the transport of ions/electrons during the catalytic reaction.

中文翻译:

将金纳米簇限制在高度缺陷的石墨层中以增强甲醇的电氧化反应

像金一样好:制备了一个Au @ C纳米复合材料,该复合材料包含限制在几层高度缺陷的石墨笼中的3–5 nm金簇;该纳米复合材料显示出高催化活性和优异的甲醇电氧化稳定性。有缺陷的石墨层阻止了金团簇的化学/热粗化,并且还为催化反应期间的离子/电子传输提供了有效的渗透通道。
更新日期:2017-11-08
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