当前位置：
X-MOL 学术
›
Tetrahedron Lett.
›
论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Transition metal mediated selective C vs N arylation of 2-aminonaphthoquinone and its application toward the synthesis of benzocarbazoledione
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2017-11-01 , DOI: 10.1016/j.tetlet.2017.10.075 Polu Ashok , Andivelu Ilangovan
中文翻译：
过渡金属介导的2-氨基萘醌选择性C vs N芳基化及其在苯并咔唑二酮合成中的应用
更新日期：2017-11-01
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2017-11-01 , DOI: 10.1016/j.tetlet.2017.10.075 Polu Ashok , Andivelu Ilangovan
|
Selective C vs N-arylation of 2-aminonaphthoquinone was achieved using different transition metal salts and arylboronic acids. Mn(OAc)3·2H2O provided C-arylated product whereas NiCl2·6H2O and Cu(OAc)2·H2O provided N-mono arylated and N,N-diarylated products respectively. Usefulness of the C and N arylated product was demonstrated by converting it into benzocarbazoledione.
中文翻译：
过渡金属介导的2-氨基萘醌选择性C vs N芳基化及其在苯并咔唑二酮合成中的应用
使用不同的过渡金属盐和芳基硼酸可实现2-氨基萘醌的选择性C对N-芳基化。Mn（OAc）3 ·2H 2 O提供C-芳基化产物，而NiCl 2 ·6H 2 O和Cu（OAc）2 ·H 2 O分别提供N-单芳基化产物和N，N-二芳基化产物。通过将C和N芳基化产物转化为苯并咔唑二酮，证明了其有用性。
京公网安备 11010802027423号