A pair of homochiral porous supramolecular organic frameworks (JLU-SOF1-R and JLU-SOF1-S) has been assembled from brand-new enantiopure blocks via hydrogen bonding and π–π interactions. The frameworks not only maintain crystallinity well until 250 °C but also exhibit a steep slope N₂ adsorption isotherm at 77 K with moderately high surface areas, indicating that the new materials own robust structure and permanent porosity. JLU-SOF1-R shows excellent adsorption capacity for CO₂ and C₂H₆ at ambient conditions. Remarkably, the material takes up a significant amount of CO₂, up to 213 cm³ g^–1 at 195 K under 1 bar. Furthermore, JLU-SOF1-R exhibits high selectivity toward CO₂ over N₂ and CH₄ as well as C₂H₆ over CH₄.

中文翻译：

---

具有明显CO ₂捕获和CO ₂ / N ₂选择性的手性多孔超分子有机骨架的自组装

从全新的对映纯嵌段通过氢键和π-π相互作用组装了一对同手性多孔超分子有机骨架（JLU-SOF1-R和JLU-SOF1-S）。该框架不仅在250°C之前保持良好的结晶度，而且在77 K时具有陡峭的N ₂吸附等温线，具有中等高的表面积，表明新材料具有坚固的结构和永久的孔隙率。JLU-SOF1-R在环境条件下对CO ₂和C ₂ H ₆表现出优异的吸附能力。值得注意的是，该材料吸收了大量的CO ₂，最高达213 cm ³ g ^–1在195 K下1 bar下。此外，JLU-SOF1-R展品朝向CO高选择性₂在N ₂和CH ₄，以及为C ₂ H ^ ₆超过CH ₄。