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P3-type K0.33Co0.53Mn0.47O2·0.39H2O: a novel bifunctional electrode for Na-ion batteries
Materials Horizons ( IF 13.3 ) Pub Date : 2017-08-07 00:00:00 , DOI: 10.1039/c7mh00512a
Sai Wang 1, 2, 3, 4, 5 , Tao Sun 5, 6, 7, 8, 9 , Shuang Yuan 5, 6, 7, 8, 9 , Yun-hai Zhu 1, 2, 3, 4, 5 , Xin-bo Zhang 5, 6, 7, 8, 9 , Jun-min Yan 1, 2, 3, 4, 5 , Qing Jiang 1, 2, 3, 4, 5
Affiliation  

A novel electrode material, P3-type K0.33Co0.53Mn0.47O2·0.39H2O (KCM), is synthesized through an easily-operated sol–gel method and it delivers considerable Na ion storage abilities when employed as both a cathode and an anode in NIBs. As a cathode, the compound displays remarkable average voltage potentials (over 3 V) and a high discharge capacity (114 mA h g−1 at 100 mA g−1). As an anode, a safe and ideal average voltage potential (0.53 V), a high discharge capacity (174 mA h g−1), and a long cycle life (950 cycles at 500 mA g−1) are also delivered together. In addition, a KCM-based full cell is subsequently built and even without any optimization it can still exhibit a high energy density (91 W h kg−1) accompanied by a long cycle performance (100 cycles at 100 mA g−1).

中文翻译:

P3型K 0.33 Co 0.53 Mn 0.47 O 2 ·0.39H 2 O:用于Na离子电池的新型双功能电极

一种新型的电极材料,P3型K 0.33 Co 0.53 Mn 0.47 O 2 ·0.39H 2 O(KCM),是通过易于操作的溶胶-凝胶法合成的,当同时用作阴极时,它具有相当大的Na离子存储能力NIB中的阳极。作为阴极,该化合物显示显着的平均电压电势(超过3 V)和放电容量高(114毫安汞柱-1在100mA克-1)。作为阳极,安全且理想的平均电压电势(0.53 V),高放电容量(174 mA hg -1)和长循环寿命(在500 mA g -1时为950个循环))也一起提供。另外,随后构建了基于KCM的全电池,即使没有进行任何优化,它仍然可以显示出高能量密度(91 W h kg -1),并具有长循环性能(在100 mA g -1时可以循环100次)。
更新日期:2017-10-30
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