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Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh3)3 (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C6H3-2,6-Trip2)GeCl (Trip = 2,4,6-iPr3C6H2)
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2017-10-26 10:06:57 , DOI: 10.1002/ejic.201700991 Peng Nie 1 , Qian Yu 1 , Hongping Zhu 1 , Ting-Bin Wen 1
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2017-10-26 10:06:57 , DOI: 10.1002/ejic.201700991 Peng Nie 1 , Qian Yu 1 , Hongping Zhu 1 , Ting-Bin Wen 1
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Reactions of MXCl(PPh3)3 (M = Ru, Os; X = Cl, H) with chlorogermylene (C6H3-2,6-Trip2)GeCl gave dichlorogermyl complexes (PPh3)XMGeCl2(C6H3-2-{η6-Trip}-6-Trip) through insertion of the germylene into the M–Cl bonds followed by η6-coordination of one Trip group to the Ru/Os center. The reaction on OsHCl(PPh3)3 also afforded the unexpected minor product Os(H)(PPh2C6H4)GeCl(C6H3-2-{η6-Trip}-6-Trip).
中文翻译：
MXCl（PPh3）3（M = Ru，Os; X = Cl，H）与三苯基氯锗烯（C6H3-2,6-Trip2）GeCl（Trip = 2,4,6-iPr3C6H2 ）
MXCl（PPh 3）3（M = Ru，Os; X = Cl，H）与氯亚甲基二甲苯（C 6 H 3 -2,6-Trip 2）GeCl的反应生成二氯锗烷基络合物（PPh 3）XMGeCl 2（C 6 H 3 -2- {η 6 -Trip} -6-跳闸）通过锗烯到M-Cl键的插入，随后η 6之一-coordination旅行组到的Ru / O的中心。在OsHCl（PPh 3）3上反应也得到了意外的副产物Os（H）（PPh 2 C 6 H 4）GeCl（C 6 H 3-2- {η 6 -Trip} -6-跳闸）。
更新日期：2017-10-27
中文翻译：
MXCl（PPh3）3（M = Ru，Os; X = Cl，H）与三苯基氯锗烯（C6H3-2,6-Trip2）GeCl（Trip = 2,4,6-iPr3C6H2 ）
MXCl（PPh 3）3（M = Ru，Os; X = Cl，H）与氯亚甲基二甲苯（C 6 H 3 -2,6-Trip 2）GeCl的反应生成二氯锗烷基络合物（PPh 3）XMGeCl 2（C 6 H 3 -2- {η 6 -Trip} -6-跳闸）通过锗烯到M-Cl键的插入，随后η 6之一-coordination旅行组到的Ru / O的中心。在OsHCl（PPh 3）3上反应也得到了意外的副产物Os（H）（PPh 2 C 6 H 4）GeCl（C 6 H 3-2- {η 6 -Trip} -6-跳闸）。
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