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Two KBBF-Type Beryllium Borates MBe2B2O6 (M = Sr, Ba) with a Three-Dimensional (Be2B2O6)∞ Network
Inorganic Chemistry ( IF 4.6 ) Pub Date : 2017-09-25 00:00:00 , DOI: 10.1021/acs.inorgchem.7b01743
Zhi Fang 1, 2 , Fei Liang 1, 2 , Mingjun Xia 1 , Lijuan Liu 1 , Qian Huang 1, 2 , Shu Guo 1, 2 , Xiaoyang Wang 1 , Zheshuai Lin 1 , Chuangtian Chen 1
Affiliation  

Two new polyborates, BaBe2B2O6 and SrBe2B2O6, in a three-dimensional (Be2B2O6) network featuring KBBF-type two-dimensional planes are synthesized. Compared with KBBF, both compounds possess comparable optical birefringence and deep-ultraviolet (deep-UV) cutoff edges and exhibit better bulk growth habits owing to their three-dimensional networks, which make them applicable deep-UV optical materials.

中文翻译:

两个KBBF型铍硼酸盐MBe 2 B 2 O 6(M = Sr,Ba),具有三维(Be 2 B 2 O 6网络

在具有KBBF型二维平面的三维(Be 2 B 2 O 6网络中,合成了两个新的多硼酸盐BaBe 2 B 2 O 6和SrBe 2 B 2 O 6。与KBBF相比,这两种化合物都具有可比的光学双折射和深紫外线(deep-UV)截止边缘,并且由于它们的三维网络而具有更好的整体生长习惯,这使它们适用于深紫外线光学材料。
更新日期:2017-09-25
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