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Single Turnover at Molecular Polymerization Catalysts Reveals Spatiotemporally Resolved Reactions
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-09-25 05:24:45 , DOI: 10.1002/anie.201708284
Quinn T. Easter , Suzanne A. Blum 1
Affiliation  

Singled out: Single-turnover detection has enabled the spatiotemporal resolution of individual reactions within growing polymers. The addition of a spectator fluorophore to the polymerization of norbornene enabled individual monomer reactions at an industrially important molecular ruthenium ring-opening metathesis polymerization catalyst to be observed as a bright-green point flash by fluorescence microscopy.

中文翻译:

分子聚合催化剂的单周转量显示时空分辨的反应

独树一帜:单周转检测已使生长中的聚合物中单个反应的时空分辨率得以实现。在降冰片烯的聚合反应中加入一种旁观者荧光团,使得在工业上重要的分子钌开环复分解聚合催化剂上的单个单体反应可以通过荧光显微镜观察为亮绿色点的闪光。
更新日期:2017-09-25
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