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Electro-kinetic Separation of Rare Earth Elements Using a Redox-Active Ligand
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-09-25 01:51:14 , DOI: 10.1002/anie.201706894
Huayi Fang 1 , Bren E. Cole 1 , Yusen Qiao 1 , Justin A. Bogart 1 , Thibault Cheisson 1 , Brian C. Manor 1 , Patrick J. Carroll 1 , Eric J. Schelter 1
Affiliation  

Let′s go kinetic: The separation of rare earth elements not by thermodynamic but by kinetic methods is feasible based on the difference of the oxidation rates of [RE(TriNOx)thf]/[RE(TriNOx)] upon oxidation with [Cp2Fe][BArF]. TriNOx3−=[{2-(tBuN(O))C6H4CH2}3N]3−; BArF=tetra[3,5-bis(trifluoromethyl)phenyl]borate.

中文翻译:

氧化还原活性配体对稀土元素进行电动分离

动力学:通过[Cp 2氧化] [RE(TriNOx)thf] / [RE(TriNOx)]的氧化速率的差异,不通过热力学而是通过动力学方法分离稀土元素是可行的。Fe] [BAr F ]。TriNOx 3-= [{2-(t BuN(O))C 6 H 4 CH 2 } 3 N] 3- ; BAr F=四[3,5-双(三氟甲基)苯基]硼酸酯。
更新日期:2017-09-25
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