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Valence Interconversion of Octahedral Nickel(II/III/IV) Centers
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-09-22 06:30:57 , DOI: 10.1002/anie.201708169
Masahiro Kouno 1 , Nobuto Yoshinari 1 , Naoto Kuwamura 1 , Kohei Yamagami 2 , Akira Sekiyama 2 , Mitsutaka Okumura 1 , Takumi Konno 1
Affiliation  

Bridge over troubled water: A series of S-bridged RhNiRh trinuclear complexes capable of supporting an octahedral nickel center in three different oxidation states (+2, +3, +4) have been isolated. Oxidation state interconversion is accompanied by changes in color, magnetism, and geometric Jahn–Teller distortions, with retention of the trinuclear structure.

中文翻译:

八面体镍(II / III / IV)中心的价互变

在有问题的水上架桥:已分离出一系列能够在三种不同氧化态(+ 2,+ 3,+ 4)下支持八面体镍中心的S桥RhNiRh三核配合物。氧化态相互转换伴随着颜色,磁性和几何Jahn-Teller变形的变化,并保留了三核结构。
更新日期:2017-09-23
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