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Mononuclear Ruthenium and Osmium Complexes with a Bicyclic Guanidinate Ligand: Synthesis and Catalytic Behavior in Olefin Isomerization Processes
European Journal of Inorganic Chemistry ( IF 2.3 ) Pub Date : 2017-09-22 05:05:37 , DOI: 10.1002/ejic.201700727
Sebastián A. Gámez-Rivera 1 , Javier Francos 1 , Javier Borge 2 , Victorio Cadierno 1
Affiliation  

New mononuclear RuII, RuIV, and OsII guanidinate complexes, derived from 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine, have been synthesized and successfully employed as catalysts for the isomerization of allylic alcohols and estragole in both organic and aqueous media.

中文翻译:

具有双环胍盐配体的单核钌和O配合物:烯烃异构化过程中的合成和催化行为。

从1,3,4,6,7,8-hexahydro-2 H -pyrimido [1,2- a ] pyrimidine衍生的新单核Ru II,Ru IV和Os II胍盐配合物已被合成并成功地用作在有机和水性介质中烯丙基醇和雌蕊异构化的催化剂。
更新日期:2017-09-22
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