Inexpensive energy storage with impeded capacity fading is the goal for today's consumer market. An oxide-based sodium battery electrode is an inexpensive candidate, although it does not solve the fading issue. Here, the fading issue has been resolved by understanding the electrochemical stability followed by material modification. An exfoliated metal oxide (α-MoO₃) maintaining good crystallinity, contouring a stable material phase, is investigated to ameliorate the storage properties. Herein, we describe an amenable technique, in situ impedance mapping, to discern the electrochemical stability just after cell fabrication. The result reflects an initial OCV instability which is depicted as a regular increase in R_ct. Hence, sufficient rest (30 h) is imposed to reach a stable OCV, after which the anode is subjected to capture Na-ions. In conjunction with an inexpensive, additive-free organic electrolyte system, the modified anode material (rGO–MoO₃) performs reversibly to store ∼0.75 A h mass specific (gm) capacity with adequate capacity retention until 100 cycles. We believe that the understanding and adoptable appraisal of impedance mapping will advance the next generation of energy storage systems.

中文翻译：

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MoO ₃剥落阳极中先进的钠储存性能：通过原位阻抗映射提高稳定性和性能

廉价的储能和受阻的容量衰减是当今消费市场的目标。尽管不能解决褪色问题，但是基于氧化物的钠电池电极是一种廉价的选择。在这里，褪色问题已通过理解电化学稳定性和随后的材料改性得以解决。剥落的金属氧化物（α-的MoO ₃）保持良好的结晶性，轮廓稳定的物质相，进行了研究以改善存储性能。在这里，我们描述了一种可改进的技术，即原位阻抗映射，以识别刚制造出电池后的电化学稳定性。结果反映了最初的OCV不稳定性，它表示为R _ct的定期增加。因此，要施加足够的静置时间（30 h）以达到稳定的OCV，然后使阳极经受捕获的Na离子。结合廉价的，无添加剂的有机电解质系统，改性阳极材料（rGO–MoO ₃）可逆地运行，可存储约0.75 A h的质量比（gm）容量，并具有足够的容量保持能力，直至100个循环。我们相信，对阻抗映射的理解和可采用的评估将推动下一代储能系统的发展。