A synthetic method of copper-catalyzed silylperoxidation of α,β-unsaturated carbonyl compounds and conjugated enynes has been developed. The realization of silylperoxidation of the carbon–carbon double bond permits direct access to silicon-containing peroxy products in moderate to good yields. Furthermore, this protocol distinguishes itself by operational simplicity and exhibiting good tolerance of a wide scope of functional groups. This strategy provides an efficient approach to the 1,2-difunctionalization of α,β-unsaturated carbonyl compounds and conjugated enynes.

中文翻译：

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铜催化的α，β-不饱和酮，酯，酰胺和共轭烯炔的甲硅烷基过氧化反应

开发了铜催化α，β-不饱和羰基化合物和共轭烯炔的甲硅烷基过氧化的合成方法。碳-碳双键的甲硅烷基过氧化的实现允许以中等到良好的产率直接获得含硅的过氧产物。此外，该协议以其操作简单性和对各种功能组的良好耐受性而独树一帜。该策略为α，β-不饱和羰基化合物和共轭烯炔的1,2-双官能化提供了有效途径。