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Graphene-Supported Pyrene-Modified Cobalt Corrole with Axial Triphenylphosphine for Enhanced Hydrogen Evolution in pH 0–14 Aqueous Solutions
ChemSusChem ( IF 8.4 ) Pub Date : 2017-09-21 07:51:34 , DOI: 10.1002/cssc.201701196
Xialiang Li 1 , Haitao Lei 1 , Xiaojun Guo 1 , Xueli Zhao 1 , Shuping Ding 1 , Xueqing Gao 1 , Wei Zhang 1 , Rui Cao 1, 2
Affiliation  

In the company of corroles: Graphene-supported cobalt corroles are active and stable catalysts for the hydrogen evolution reaction in water over a wide pH range of 0–14. The introduction of a pyrenyl group to the corrole macrocycle and the use of a triphenylphosphine axial ligand on Co improve the catalytic efficiency significantly.

中文翻译:

石墨烯支持的P修饰的钴醇盐与轴向三苯基膦的作用,可在pH 0-14的水溶液中增强氢的释放

在corroles公司中:石墨烯负载的钴coroles是在0至14的宽pH范围内在水中进行氢气分解反应的活性和稳定催化剂。将cor烯基引入到Corrole大环中以及在Co上使用三苯基膦轴向配体可显着提高催化效率。
更新日期:2017-09-21
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