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Nickel hexacyanoferrate/carbon composite as a high-rate and long-life cathode material for aqueous hybrid energy storage
Chemical Communications ( IF 4.9 ) Pub Date : 2017-09-05 00:00:00 , DOI: 10.1039/c7cc04914e
Dapeng Zhang 1, 2, 3, 4, 5 , Junshu Zhang 1, 2, 3, 4, 5 , Zengxu Yang 1, 2, 3, 4, 5 , Xiaochuan Ren 6, 7, 8, 9 , Hongzhi Mao 1, 2, 3, 4, 5 , Xianfeng Yang 9, 10, 11, 12 , Jian Yang 1, 2, 3, 4, 5 , Yitai Qian 1, 2, 3, 4, 5
Affiliation  

A nickel hexacyanoferrate (NiHCF)/carbon composite is prepared to realize reduced structure vacancies and enhanced conductivity simultaneously. The resultant composite as a cathode material exhibits good capacity retentions both for rate capability (93% of that at 0.1 A g−1 for 2 A g−1) and cycle stability (94% after 900 cycles at 0.5 A g−1). This feature is also kept in an aqueous hybrid energy storage device, after coupling with rGO as the anode. After 5000 cycles at 2 A g−1, 94% of the initial capacity is preserved, exhibiting extraordinary stability at high rates.

中文翻译:

六氰合铁酸镍/碳复合材料作为高速率,长寿命的阴极材料,用于水性混合能源存储

制备了六氰合铁酸镍(NiHCF)/碳复合材料,可同时实现减少的结构空位和增强的电导率。所得的复合材料作为正极材料在速率能力(对于2 A g -1为0.1 A g -1时为93%)和循环稳定性(在0.5 A g -1下900次循环后为94%)均显示出良好的容量保持率。在与rGO作为阳极耦合之后,该功能也保留在水性混合能量存储设备中。在2 A g -1下进行5000次循环后,保留了94%的初始容量,在高速率下表现出非凡的稳定性。
更新日期:2017-09-21
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