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Going against the flow: Os(II)-to-Ru(II) energy transfer in rod-like polypyridyl chromophore
Chemical Communications ( IF 4.9 ) Pub Date : 2017-08-02 00:00:00 , DOI: 10.1039/c7cc03541a Baptiste Laramée-Milette 1, 2, 3, 4, 5 , Garry S. Hanan 1, 2, 3, 4, 5
Chemical Communications ( IF 4.9 ) Pub Date : 2017-08-02 00:00:00 , DOI: 10.1039/c7cc03541a Baptiste Laramée-Milette 1, 2, 3, 4, 5 , Garry S. Hanan 1, 2, 3, 4, 5
Affiliation
The judicious design of a unique mixed-metal Ru–Os molecular rod led to the first photoinduced energy transfer from osmium-to-ruthenium in a polypyridyl complex. The absorbed light is directed from the osmium metal center to the peripheral ruthenium moieties, where only the low energy luminescence from the heteroleptic ruthenium phen-hpp complex was observed.
中文翻译:
逆流:棒状多吡啶基发色团中Os(II)-Ru(II)的能量转移
独特的混合金属Ru-Os分子棒的明智设计导致了在多吡啶基络合物中从-到钌的首次光诱导能量转移。吸收的光从from金属中心射向外围钌部分,在该处仅观察到来自杂合钌phen-hpp络合物的低能发光。
更新日期:2017-09-21
中文翻译:
逆流:棒状多吡啶基发色团中Os(II)-Ru(II)的能量转移
独特的混合金属Ru-Os分子棒的明智设计导致了在多吡啶基络合物中从-到钌的首次光诱导能量转移。吸收的光从from金属中心射向外围钌部分,在该处仅观察到来自杂合钌phen-hpp络合物的低能发光。