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Ag@CoxP Core–Shell Heterogeneous Nanoparticles as Efficient Oxygen Evolution Reaction Catalysts
ACS Catalysis ( IF 12.9 ) Pub Date : 2017-09-20 00:00:00 , DOI: 10.1021/acscatal.7b02341
Yuhui Hou 1 , Yipu Liu 2 , Ruiqin Gao 2 , Qiuju Li 2 , Huizhang Guo 3 , Anandarup Goswami 4, 5 , Radek Zboril 5 , Manoj B. Gawande 5 , Xiaoxin Zou 2
Affiliation  

We present a facile synthetic method that yields Ag@CoxP core–shell-type heterogeneous nanostructures with excellent oxygen evolution reaction (OER) activity. This nanocatalyst can deliver a current density of 10 mA/cm2 at a small overpotential of 310 mV and exhibits high catalytic stability. Additionally, the catalytic activity of Ag@CoxP is 8 times higher than that of the Co2P nanoparticles, owing primarily to the strong electronic interaction between the Ag core and the CoxP shell.

中文翻译:

Ag @ Co x P核-壳多相纳米粒子作为高效氧释放反应催化剂

我们提出了一种简便的合成方法,该方法可产生具有出色的氧释放反应(OER)活性的Ag @ Co x P核-壳型异质纳米结构。该纳米催化剂在310mV的小的过电势下可以提供10mA / cm 2的电流密度,并且表现出高的催化稳定性。另外,Ag @ Co x P的催化活性比Co 2 P纳米颗粒的催化活性高8倍,这主要归因于Ag核与Co x P壳之间的强电子相互作用。
更新日期:2017-09-20
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