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Well-defined multiblock poly(vinylidene fluoride) and block copolymers thereof: a missing piece of the architecture puzzle
Chemical Communications ( IF 4.9 ) Pub Date : 2017-09-13 00:00:00 , DOI: 10.1039/c7cc06122f Sanjib Banerjee 1, 2, 3, 4, 5 , Yogesh Patil 1, 2, 3, 4, 5 , Olinda Gimello 1, 2, 3, 4, 5 , Bruno Ameduri 1, 2, 3, 4, 5
Chemical Communications ( IF 4.9 ) Pub Date : 2017-09-13 00:00:00 , DOI: 10.1039/c7cc06122f Sanjib Banerjee 1, 2, 3, 4, 5 , Yogesh Patil 1, 2, 3, 4, 5 , Olinda Gimello 1, 2, 3, 4, 5 , Bruno Ameduri 1, 2, 3, 4, 5
Affiliation
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Unprecedented synthesis of multiblock poly(vinylidene fluoride) (PVDF, up to 16
300 g mol−1) with narrow-dispersity blocks (Đ = 1.26) mediated by a fluorinated cyclic xanthate via reversible addition–fragmentation chain transfer (RAFT) polymerization is reported. The as-synthesized multiblock PVDF was employed as a macroRAFT agent to prepare valuable multiblock copolymers with potential applications in emerging areas.
中文翻译：
定义明确的多嵌段聚偏二氟乙烯及其嵌段共聚物：建筑难题的缺失部分
据报道，通过可逆的加成-断裂链转移（RAFT）聚合反应，氟化环黄药介导了具有窄分散性嵌段（Đ = 1.26）的多嵌段聚偏二氟乙烯（PVDF，高达16300 g mol -1）的空前合成。。合成后的多嵌段PVDF被用作macroRAFT剂，以制备有价值的多嵌段共聚物，并在新兴领域有潜在的应用。
更新日期：2017-09-20
300 g mol−1) with narrow-dispersity blocks (Đ = 1.26) mediated by a fluorinated cyclic xanthate via reversible addition–fragmentation chain transfer (RAFT) polymerization is reported. The as-synthesized multiblock PVDF was employed as a macroRAFT agent to prepare valuable multiblock copolymers with potential applications in emerging areas.
中文翻译：
定义明确的多嵌段聚偏二氟乙烯及其嵌段共聚物：建筑难题的缺失部分
据报道，通过可逆的加成-断裂链转移（RAFT）聚合反应，氟化环黄药介导了具有窄分散性嵌段（Đ = 1.26）的多嵌段聚偏二氟乙烯（PVDF，高达16
300 g mol -1）的空前合成。。合成后的多嵌段PVDF被用作macroRAFT剂，以制备有价值的多嵌段共聚物，并在新兴领域有潜在的应用。
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