Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane,Dalton Transactions

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Isomerisation, reactivity and coordination chemistry of a new hybrid, multi-functional phosphazane
Dalton Transactions ( IF 4 ) Pub Date : 2017-09-11 00:00:00 , DOI: 10.1039/c7dt03074f
Alex J. Plajer _{1,

2,

3,

4} , Kevin Bold _{1,

2,

3,

4} , Felix J. Rizzuto _{1,

2,

3,

4} , Raúl García-Rodríguez _{5,

6,

7,

8,

9} , Tanya K. Ronson _{1,

2,

3,

4} , Dominic S. Wright _{1,

2,

3,

4}

Affiliation

The unsymmetric P^III/P^V cyclodiphosphazane framework [(S [double bond, length as m-dash]

)(H)P(μ-N^tBu)₂PNH^tBu] (2) provides entry into the mixed chalgogenide dianion [(S)P(μ-N^tBu)₂P(Se)N^tBu]²⁻, and unique insight into the mechanisms of cis/trans isomerism in phosph(III)- and phosph(V)-azanes.

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