Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex,Dalton Transactions

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Direct transformation of 2-acetylpyridine oxime esters into α-oxygenated imines in an Ir(III) complex
Dalton Transactions ( IF 4 ) Pub Date : 2017-08-24 00:00:00 , DOI: 10.1039/c7dt02528a
Hiroyuki Takahashi _{1,

2,

3,

4,

5} , Shintaro Kodama _{1,

2,

3,

4,

5} , Youichi Ishii _{1,

2,

3,

4,

5}

Affiliation

2-Acetylpyridine oxime esters are transformed into the corresponding α-oxygenated imines in an Ir(III) complex under mild conditions, where the selective metal coordination of the imino group effectively promotes tautomerization of the oxime esters into the N-oxyenamines and the subsequent rearrangement.

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