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A route to robust thioether-functionalized MOF solid materials displaying heavy metal uptake and the ability to be further oxidized
Dalton Transactions ( IF 4 ) Pub Date : 2017-08-14 00:00:00 , DOI: 10.1039/c7dt02334k
Guo-Wei Xiao 1, 2, 3, 4, 5 , Teng-Fei Chen 1, 2, 3, 4, 5 , Xin-Zhan Sun 1, 2, 3, 4, 5 , Hui Guo 1, 2, 3, 4, 5 , Zhong-Feng Li 1, 2, 3, 4, 5 , Yu-Heng Deng 1, 2, 3, 4, 5 , Chong-Qing Wan 1, 2, 3, 4, 5
Affiliation  

Here we developed a facile solvent-assisted ligand exchange method for synthesizing thioether-containing hybrid metal–organic frameworks (MOFs) that cannot be made using direct synthesis. Such a tailored approach provides an alternative method to achieve thioether-based MOFs and its oxidation-decorated materials. These materials showed the ability to take up heavy metals from solution and the ability to capture CO2.

中文翻译:

展现出强大的硫醚官能化MOF固体材料的途径,该材料显示出对重金属的吸收能力以及被进一步氧化的能力

在这里,我们开发了一种简便的溶剂辅助配体交换方法,用于合成含硫醚的杂化金属-有机骨架(MOF),而这种合成不能直接使用合成方法完成。这种量身定制的方法为实现基于硫醚的MOF及其氧化修饰材料提供了另一种方法。这些材料显示出能够从溶液中吸收重金属的能力以及捕获CO 2的能力。
更新日期:2017-09-20
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