Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: synthesis and applications,Dalton Transactions

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Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: synthesis and applications
Dalton Transactions ( IF 4 ) Pub Date : 2017-06-27 00:00:00 , DOI: 10.1039/c7dt02126g
Tapas Ghatak _{1,

2,

3,

4} , Shani Drucker _{1,

2,

3,

4} , Natalia Fridman _{1,

2,

3,

4} , Moris S. Eisen _{1,

2,

3,

4}

Affiliation

Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(IV) complexes of the type Cp*₂Th(L)(CH₃). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.

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