Carbon nitride assisted chemoselective C–H bond photo-oxidation of alkylphenolethoxylates in water medium,Green Chemistry

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Carbon nitride assisted chemoselective C–H bond photo-oxidation of alkylphenolethoxylates in water medium
Green Chemistry ( IF 9.8 ) Pub Date : 2017-08-11 00:00:00 , DOI: 10.1039/c7gc01588g
M. Ilkaeva _{1,

2,

3,

4,

5} , I. Krivtsov _{1,

2,

3,

4,

5} , E. Bartashevich _{6,

7,

8,

9} , S. A. Khainakov _{4,

5,

10,

11} , J. R. García _{1,

2,

3,

4,

5} , E. Díaz _{4,

5,

11,

12} , S. Ordóñez _{4,

5,

11,

12}

Affiliation

The unprecedented ability of g-C₃N₄ to chemoselectively photo-oxidise the methyl group of 2-(4-methylphenoxy)ethanol instead of the easily oxidised oxyethanol fragment has been demonstrated. When g-C₃N₄ is treated with H₂O₂, its selectivity enhances due to the blocking of surface sites responsible for the adsorption and the subsequent oxidation of the oxyethanol substituent.

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