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Preorganization and Cooperation for Highly Efficient and Reversible Capture of Low-Concentration CO2 by Ionic Liquids
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2017-09-19 07:46:29 , DOI: 10.1002/anie.201706280
Yanjie Huang 1 , Guokai Cui 1, 2 , Yuling Zhao 1 , Huiyong Wang 1 , Zhiyong Li 1 , Sheng Dai 2, 3 , Jianji Wang 1
Affiliation  

Two for one: A novel preorganization and cooperation strategy has been designed for a superior capacity (22 wt %, 1.65 mol mol−1) to capture low-concentration CO2 (10 vol. % CO2 in N2) by imide-based ionic liquids with excellent reversibility (16 cycles). Multiple-site cooperative interactions between CO2 and active sites in the preorganized anion are operative.

中文翻译:

离子液体高效可逆地捕集低浓度CO2的预组织与合作

一对二:设计了一种新颖的预组织和合作策略,以通过基于酰亚胺的溶液捕获低浓度的CO 2(N 2中的10 vol。%CO 2)来捕获低浓度的CO 2(22 wt%,1.65 mol mol -1)。具有优异可逆性(16个循环)的离子液体。在预先组织的阴离子中,CO 2和活性位点之间的多位协作相互作用是有效的。
更新日期:2017-09-19
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