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Alkylation of cyclic amines with alcohols catalyzed by Ru(II) complexes bearing N-Heterocyclic carbenes
Tetrahedron ( IF 2.1 ) Pub Date : 2017-09-18 , DOI: 10.1016/j.tet.2017.09.027
Öznur Doğan Ulu , Nevin Gürbüz , İsmail Özdemir

This paper includes the synthesis of 2-(1,3-dioxane-2-yl)ethyl substituted benzimidazole substituted N-heterocyclic carbenes precursors and their ruthenium complexes. Synthesized compounds were characterized by elemental analysis and NMR spectroscopy. All complexes have been tested in the alkylation of pyrrolidine and morpholine with alcohols, showing an excellent activity in this reaction.



中文翻译:

带有N-杂环卡宾的Ru(II)配合物催化环胺与醇的烷基化

本文包括2-(1,3-二恶烷-2-基)乙基取代的苯并咪唑取代的N-杂环卡宾前体及其钌配合物的合成。合成的化合物通过元素分析和NMR光谱进行表征。所有配合物均已在吡咯烷和吗啉与醇的烷基化反应中进行了测试,在该反应中显示出出色的活性。

更新日期:2017-09-18
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