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Cover Feature: Dehydrogenase‐Catalyzed Oxidation of Furanics: Exploitation of Hemoglobin Catalytic Promiscuity (ChemSusChem 18/2017)
ChemSusChem ( IF 8.4 ) Pub Date : 2017-09-18 , DOI: 10.1002/cssc.201701701
Hao-Yu Jia 1 , Min-Hua Zong 1 , Hui-Lei Yu 2 , Ning Li 1
Affiliation  

The Inside Cover picture shows a new and effective in situ regeneration system for oxidized nicotinamide cofactors [NAD(P)+] based on catalytic promiscuity of hemoglobin (Hb). This NAD(P)+ regeneration system has good applicability in oxidation reactions catalyzed by dehydrogenases (DHs) such as horse liver alcohol dehydrogenase (HLADH). The target acids (e.g., 2,5‐furandicarboxylic acid, FDCA) were prepared from bio‐based furanics with moderate‐to‐good yields in the Hb/HLADH parallel cascade reactions. More details can be found in the Communication by Jia et al. on page 3524 in Issue 18, 2017 (DOI: 10.1002/cssc.201701288).
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中文翻译:

封面功能:脱氢酶催化的呋喃氧化:利用血红蛋白催化混杂(ChemSusChem 18/2017)

内部封面图片显示了一种基于血红蛋白(Hb)催化混杂性的氧化烟酰胺辅因子[NAD(P)+ ]的新型有效原位再生系统。该NAD(P)+再生系统在由马肝醇脱氢酶(HLADH)等脱氢酶(DHs)催化的氧化反应中具有良好的适用性。目标酸(例如2,5-呋喃二甲酸,FDCA)是由生物基呋喃制备的,在Hb / HLADH平行级联反应中产率中等至良好。可以在Jia等人的《通讯》中找到更多详细信息。就在第18期,2017年3524页(:10.1002 / cssc.201701288 DOI)。
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更新日期:2017-09-18
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