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Development of Imino‐λ3‐iodanes with Improved Reactivity for Metal‐Free [2+2+1] Cycloaddition‐Type Reactions
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2017-09-28 , DOI: 10.1002/adsc.201700934
Takafumi Baba 1 , Shunsuke Takahashi 1 , Yui Kambara 1 , Akira Yoshimura 2, 3 , Victor N. Nemykin 4 , Viktor V. Zhdankin 2 , Akio Saito 1
Affiliation  

Aiming at the enhancement of electrophilicity of imino‐λ3‐iodanes, we have developed (tosylimino)pentafluorophenyl‐λ3‐iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl‐λ3‐iodane in the [2+2+1]‐type synthesis of imidazoles.

中文翻译:

开发具有改进的反应性的无金属[2 + 2 + 1]环加成型反应的Imino-λ3-碘酮

针对亚氨基λ的亲电性的提高3个-iodanes,我们已经开发(tosylimino)五氟苯基-λ 3 -iodane,其表现出优异的反应性相比于通常使用的(tosylimino)苯基λ 3 -iodane在[2+ 2 + 1]型咪唑合成。
更新日期:2017-09-28
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