The photochemical metal-free carboamidation of aryl radicals has been exploited for the preparation of aromatic amides, including hetero- and polyaromatic derivatives, under visible light irradiation of arylazo sulfones in the presence of isocyanides in aqueous acetonitrile. The process was useful for the smooth preparation of the antidepressant moclobemide.

中文翻译：

---

可见光驱动的无金属路线，通过异腈的自由基芳基化反应生成芳族酰胺

在芳基偶氮砜的可见光照射下，在乙腈水溶液中，在异氰酸酯存在下，芳基的无光化学金属碳酰化已被用于制备芳族酰胺，包括杂芳族和聚芳族衍生物。该方法对于顺利制备抗抑郁药莫氯贝胺是有用的。