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N-Heterocyclic Carbene Catalyzed Stereoselective Glycosylation of 2-Nitrogalactals
Organic Letters ( IF 5.2 ) Pub Date : 2017-09-14 00:00:00 , DOI: 10.1021/acs.orglett.7b02543
Jia-Lin Liu 1 , Yu-Tong Zhang 1 , Hang-Fan Liu 1 , Ling Zhou 1 , Jie Chen 1
Affiliation  

An efficient N-heterocyclic carbene catalyzed glycosylation of 2-nitrogalactals with alcohols and phenol has been developed for the first time. A wide variety of 1,2-cis-2-nitroglycosides can be obtained with good to excellent yields and high to excellent α-selectivities.

中文翻译:

N-杂环碳烯催化2-硝基半乳糖的立体选择性糖基化。

首次开发了一种有效的N-杂环卡宾催化2-硝基半乳糖与醇和苯酚的糖基化反应。可以以高至优异的产率和高至优异的α-选择性获得各种各样的1,2-顺式-2-硝基糖苷。
更新日期:2017-09-14
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