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Auto-Reduction Behavior of Cobalt on Graphitic Carbon Nitride Coated Alumina Supports for Fischer–Tropsch Synthesis
ChemCatChem ( IF 4.5 ) Pub Date : 2017-09-13 13:13:03 , DOI: 10.1002/cctc.201700613
Hunmin Park 1 , Kwang Young Kim 2 , Duck Hyun Youn 2 , Yo Han Choi 3 , Won Young Kim 1 , Jae Sung Lee 2
Affiliation  

Stay away! Graphitic carbon nitride (g-C3N4)-coated alumina (CN-Al) is investigated as a support material for a cobalt-based Fischer–Tropsch synthesis (FTS) catalyst. The g-C3N4 blocks the interaction between Co and alumina to hinder the formation of irreducible cobalt oxide species, and improves the dispersion of metallic Co species on the CN-Al support. Because of the improved dispersion and reducibility of the Co species on the CN-Al support, the catalytic FTS activity of Co/CN-Al is higher compared with the conventional Co/Al2O3 catalyst.

中文翻译:

费托合成中石墨在氮化碳涂层氧化铝载体上的自动还原行为

远离!研究了石墨化氮化碳(gC 3 N 4)包覆的氧化铝(CN-Al)作为钴基费-托合成(FTS)催化剂的载体材料。gC 3 N 4阻止了Co与氧化铝之间的相互作用,从而阻碍了不可还原的氧化钴物质的形成,并改善了金属Co物质在CN-Al载体上的分散性。由于改善了Co物种在CN-Al载体上的分散性和可还原性,因此与常规Co / Al 2 O 3催化剂相比,Co / CN-Al的催化FTS活性更高。
更新日期:2017-09-14
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