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Synthesis of Lower Olefins from Synthesis Gas over Active Carbon-Supported Iron Catalyst
Catalysis Today ( IF 5.3 ) Pub Date : 2017-09-14 , DOI: 10.1016/j.cattod.2017.09.010
Kenji Asami , Kazuki Komiyama , Kohei Yoshida , Hiroki Miyahara

Synthesis of C2-C6 lower olefins from synthesis gas was investigated through Fischer-Tropsch synthesis (FTS) reaction over active carbon-supported iron catalyst with a small amount of Cu (Fe-Cu/AC) catalysts using a fixed bed reactor at 300 °C at 2.1 MPa. Mn promoted catalyst (Fe-Cu-Mn/AC) gave high yield and selectivity to the lower olefins. Added Mn species seemed likely to locate uniformly on the AC surface to form complex oxide with iron oxide. A high yield of ca. 40% is obtainable at high H2/CO ratio of 4. The catalyst showed stable activity and selectivity for 100 h. CO2 addition in the feed gas enhances the yield further by suppressing the water gas shift reaction.



中文翻译:

活性炭负载的铁催化剂上由合成气合成低级烯烃

使用固定床反应器,通过活性炭负载的铁催化剂与少量的Cu(Fe-Cu / AC)催化剂,通过费-托合成(FTS)反应,研究了由合成气合成C 2 -C 6低级烯烃的方法。 300摄氏度,2.1兆帕。锰促进的催化剂(Fe-Cu-Mn / AC)对低级烯烃具有高收率和选择性。所添加的锰物质似乎很可能均匀地分布在AC表面上,从而与氧化铁形成复合氧化物。大约高产。在4的高H 2 / CO比下可获得40%的催化剂。催化剂在100小时内表现出稳定的活性和选择性。通过抑制水煤气变换反应,在原料气中添加CO 2可以进一步提高收率。

更新日期:2017-09-14
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