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Synthesis of Indenes that are Derived from Aldimines with Enones Under Rhodium(III) Catalysis
Asian Journal of Organic Chemistry ( IF 2.7 ) Pub Date : 2017-10-16 , DOI: 10.1002/ajoc.201700473
Sang Hoon Han 1 , Saegun Kim 1 , Neeraj Kumar Mishra 1 , Hyunjung Oh 1 , Myung Hoon Choi 2 , Dong Seok Choi 1 , Hyeon Ju Lim 1 , Dong Yeop Shin 1 , In Su Kim 1
Affiliation  

The rhodium(III)‐catalyzed C−H alkylation and intramolecular cyclization of aldimines with enones are described. This transformation provides direct access to the formation of C2‐carbonyl‐substituted indene derivatives with excellent site‐selectivity and functional group compatibility.

中文翻译:

铑(III)催化合成醛亚胺与烯酮的茚满

描述了铑(III)催化的CH烷基化和醛酮与烯酮的分子内环化。这种转变提供了直接形成具有出色的位点选择性和官能团相容性的C2-羰基取代的茚衍生物的途径。
更新日期:2017-10-16
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